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0.20 g of organic compound gave 0.5544 g...

0.20 g of organic compound gave 0.5544 g of `BaSO_(4)`. The percentage of S is

A

38

B

19

C

18

D

83

Text Solution

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The correct Answer is:
To find the percentage of sulfur (S) in the organic compound, follow these steps: ### Step 1: Determine the Molar Mass of Barium Sulfate (BaSO₄) The molar mass of BaSO₄ is given as 233 g/mol. This includes: - Barium (Ba): 137 g/mol - Sulfur (S): 32 g/mol - Oxygen (O): 16 g/mol × 4 = 64 g/mol Thus, the total is: \[ \text{Molar mass of BaSO₄} = 137 + 32 + 64 = 233 \, \text{g/mol} \] ### Step 2: Calculate the Moles of BaSO₄ Produced Using the mass of BaSO₄ obtained: \[ \text{Mass of BaSO₄} = 0.5544 \, \text{g} \] To find the moles of BaSO₄: \[ \text{Moles of BaSO₄} = \frac{\text{Mass}}{\text{Molar Mass}} = \frac{0.5544 \, \text{g}}{233 \, \text{g/mol}} \] Calculating this gives: \[ \text{Moles of BaSO₄} = 0.00238 \, \text{mol} \] ### Step 3: Determine the Moles of Sulfur in BaSO₄ From the formula of BaSO₄, we know that 1 mole of BaSO₄ contains 1 mole of sulfur. Therefore: \[ \text{Moles of S} = \text{Moles of BaSO₄} = 0.00238 \, \text{mol} \] ### Step 4: Calculate the Mass of Sulfur Using the atomic mass of sulfur (32 g/mol): \[ \text{Mass of S} = \text{Moles of S} \times \text{Atomic Mass of S} = 0.00238 \, \text{mol} \times 32 \, \text{g/mol} \] Calculating this gives: \[ \text{Mass of S} = 0.07616 \, \text{g} \] ### Step 5: Calculate the Percentage of Sulfur in the Organic Compound Using the formula for percentage: \[ \text{Percentage of S} = \left( \frac{\text{Mass of S}}{\text{Mass of Organic Compound}} \right) \times 100 \] Substituting the values: \[ \text{Percentage of S} = \left( \frac{0.07616 \, \text{g}}{0.20 \, \text{g}} \right) \times 100 \] Calculating this gives: \[ \text{Percentage of S} = 38.08\% \] ### Final Answer The percentage of sulfur in the organic compound is approximately **38%**.

To find the percentage of sulfur (S) in the organic compound, follow these steps: ### Step 1: Determine the Molar Mass of Barium Sulfate (BaSO₄) The molar mass of BaSO₄ is given as 233 g/mol. This includes: - Barium (Ba): 137 g/mol - Sulfur (S): 32 g/mol - Oxygen (O): 16 g/mol × 4 = 64 g/mol Thus, the total is: ...
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Knowledge Check

  • In an estimation of S by carius method 0.2175 g of the compound gave 0.5825 g of BaSO_(4) Percentage of S is

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