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CH(3) - undersetunderset(Cl)(|)C = CH - ...

`CH_(3) - undersetunderset(Cl)(|)C = CH - undersetunderset(O)("||")C - OCH_(3)` is named in IUPAC as :

A

Methyl -3-chloro-2-butenoate

B

Methyl 4 chloro -2-pentanoate

C

Methoxy -3-chloro butanol

D

Methoxy -2-chloro butanone

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The correct Answer is:
To determine the IUPAC name of the given compound, we will follow these steps: ### Step 1: Identify the Functional Group The given structure contains an ester functional group, which is characterized by the presence of the -COO- group. **Hint:** Look for the -COO- group to identify esters. ### Step 2: Number the Carbon Chain We will start numbering the carbon chain from the carbon of the ester group. This will help us identify the longest carbon chain and the position of the functional groups. - Start numbering from the carbon of the ester (C=O). - The numbering will be as follows: 1. Carbon of the ester (C=O) 2. Carbon next to it 3. Carbon with chlorine attached 4. Last carbon in the chain **Hint:** Always start numbering from the functional group that has the highest priority. ### Step 3: Determine the Parent Chain The longest carbon chain we have is 4 carbons long, which is called butane. However, since there is a double bond present, we will modify the name to butene. **Hint:** Count the number of carbons in the longest chain to determine the base name. ### Step 4: Identify the Position of the Double Bond The double bond is located between the 2nd and 3rd carbons. Therefore, we will specify the position of the double bond in the name as 2-butene. **Hint:** The position of the double bond is indicated by the lowest numbered carbon involved in the double bond. ### Step 5: Name the Ester Component In the case of esters, the alkyl group attached to the oxygen is named first. Here, the alkyl group is a methyl group (from -OCH₃). **Hint:** The alkyl group from the ester is named first in the IUPAC name. ### Step 6: Modify the Parent Name for Ester In the naming of esters, the "e" in the alkene name (butene) is replaced with "oate". Therefore, "butene" becomes "butenoate". **Hint:** Remember to replace the "e" in the alkene name with "oate" when naming esters. ### Step 7: Identify and Name Substituents There is a chlorine atom attached to the 3rd carbon in the chain. We will denote this as 3-chloro. **Hint:** Substituents are named with their position number before the parent name. ### Step 8: Combine All Parts to Form the Complete Name Now, we can combine all parts: - Alkyl group from the ester: methyl - Substituent: 3-chloro - Parent name: 2-butenoate Putting it all together, we get the complete IUPAC name: **methyl-3-chloro-2-butenoate**. **Final Answer:** The IUPAC name of the compound is **methyl-3-chloro-2-butenoate**.
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The IUPAC name of the compound CH_(3) - undersetunderset(OH)(|)CH -CH_(2) - oversetoverset(CH_(3))(|)undersetunderset(Cl)(|)C-CH_(3)

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NARAYNA-SOME BASIC PRINCIPLES AND TECHNIQUES-EXERCISE - III (PREVIOUS YEARS EXAMS QUESTIONS)
  1. The compound having only primary hydrogen atom is :-

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  2. The names of some compounds are given. Which one not in the IUPAC syst...

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  3. CH(3) - undersetunderset(Cl)(|)C = CH - undersetunderset(O)("||")C - O...

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  4. The general molecular formula, which represents the homologous series ...

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  5. Which of the following is the strongest base :-

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  6. Which of the following is more active in a nucleophilic substitution r...

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  7. The strongest base among the following is :-

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  8. Among the following the aromatic compound is

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  9. Which of the following compounds has the highest boiling point ?

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  10. The correct increasing order of the reactivity of halides for S(N)' re...

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  11. Arrange the following in correct order of nucleophilicity :- CH(3)-O...

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  12. Which amongst the following is the most stable carbocation :-

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  13. Which one of the following compounds is most acidic :-

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  14. Pyridine is less basic than triethylamine because .

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  15. Which of the following is more basic than aniline? .

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  16. Nucleophilic addition reaction will be most favoured in :

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  17. Which of the following presents the correct order of the acidity in th...

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  18. Arrange the following for reducing power : (a) I^(-) (b) Cl^(-...

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  19. The order of decreasing reactivity towards electrophilic reagent for t...

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  20. Which one of the following is most reactive towards electrophilic atta...

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