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A carbonyl compound (P) which gives posi...

A carbonyl compound (P) which gives positive iodoform test, undergoes reaction with MeMgBr followed by dehydration to give an olefin (Q). Ozonolysis of (Q) leads to a dicarbonyl compound (R ) which undergoes intramolecular aldol reaction to give predominantly (S).
`Poverset(1. MeMgBr)underset{:(2.H^(+)","H_(2)O),(3.H_(2)SO_(4)","Delta):}rarr Q underset(2. Zn"," H_(2)O)overset(1. O_(3))rarr R underset(2. Delta)overset(1. OH^(-))rarr S`
The structure of the carbonyl compound (P) is:

A

B

C

D

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The correct Answer is:
B
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A carbonyl compound (P) which gives positive iodoform test, undergoes reaction with MeMgBr followed by dehydration to give an olefin (Q). Ozonolysis of (Q) leads to a dicarbonyl compound (R ) which undergors intramolecular aldol reaction to give predominantly (S). Poverset(1. MeMgBr)underset{:(2.H^(+)","H_(2)O),(3.H_(2)SO_(4)","Delta):}rarr Q underset(2. Zn"," H_(2)O)overset(1. O_(3))rarr R underset(2. Delta)overset(1. OH^(-))rarr S The structure of product (S) is:

A carbonyl compound (P) which gives positive iodoform test, undergoes reaction with MeMgBr followed by dehydration to give an olefin (Q). Ozonolysis of (Q) leads to a dicarbonyl compound (R ) which undergors intramolecular aldol reaction to give predominantly (S). Poverset(1. MeMgBr)underset{:(2.H^(+)","H_(2)O),(3.H_(2)SO_(4)","Delta):}rarr Q underset(2. Zn"," H_(2)O)overset(1. O_(3))rarr R underset(2. Delta)overset(1. OH^(-))rarr S The structure of products (Q) and (R ), respectively, are:

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  8. Schemes 1 and 2 describe sequential transformation of alkynes M ...

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  9. Schemes 1 and 2 describe sequential transformation of alkynes M ...

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  14. columns 1,2, and 3 contain starting materials , reaction conditio...

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  15. The reaction of compound P with CH3 MgBr (excess) in (C2 H5 )2 O follo...

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  16. Treatment of benzene with CO/HCl in the presence of anhydrous "AlCl"(3...

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