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On electrolysis of dilute sulphuric acid...

On electrolysis of dilute sulphuric acid using platinum electrodes, the product obtained at the anode will be

A

hydrogen

B

oxygen is more reactive than nitrogen.

C

hydrogen sulphide

D

sulphur dioxide

Text Solution

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The correct Answer is:
To solve the question regarding the product obtained at the anode during the electrolysis of dilute sulfuric acid using platinum electrodes, we can follow these steps: ### Step-by-Step Solution: 1. **Understanding Electrolysis**: - Electrolysis involves passing an electric current through an electrolyte (in this case, dilute sulfuric acid, H₂SO₄) to induce a chemical reaction. 2. **Identifying the Electrolyte**: - Dilute sulfuric acid dissociates in water to produce hydrogen ions (H⁺) and sulfate ions (SO₄²⁻): \[ \text{H}_2\text{SO}_4 \rightarrow 2\text{H}^+ + \text{SO}_4^{2-} \] 3. **Determining the Electrodes**: - In electrolysis, the anode is the positive electrode where oxidation occurs, and the cathode is the negative electrode where reduction occurs. 4. **Identifying Ions at the Anode**: - At the anode, negatively charged ions (anions) are attracted. In dilute sulfuric acid, the relevant anions are hydroxide ions (OH⁻) from water and sulfate ions (SO₄²⁻). 5. **Comparing Electrode Potentials**: - The discharge of ions at the anode depends on their standard electrode potentials. The hydroxide ion (OH⁻) has a lower discharge potential compared to the sulfate ion (SO₄²⁻), meaning it is preferentially discharged. 6. **Reaction at the Anode**: - When hydroxide ions are discharged, they undergo oxidation to form oxygen gas (O₂): \[ 4\text{OH}^- \rightarrow 2\text{H}_2\text{O} + \text{O}_2 + 4e^- \] - This indicates that oxygen gas is produced at the anode. 7. **Conclusion**: - Therefore, the product obtained at the anode during the electrolysis of dilute sulfuric acid using platinum electrodes is **oxygen gas (O₂)**. ### Final Answer: The product obtained at the anode will be **oxygen gas (O₂)**. ---

To solve the question regarding the product obtained at the anode during the electrolysis of dilute sulfuric acid using platinum electrodes, we can follow these steps: ### Step-by-Step Solution: 1. **Understanding Electrolysis**: - Electrolysis involves passing an electric current through an electrolyte (in this case, dilute sulfuric acid, H₂SO₄) to induce a chemical reaction. 2. **Identifying the Electrolyte**: ...
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Knowledge Check

  • On electrolysis of dil. sulphuric acid using a platinum (Pt) electrode, the product obtained at anode will be

    A
    hydrogen gas
    B
    oxygen gas
    C
    `H_(2)S` gas
    D
    `SO_(2)` gas
  • On elctrolysis of dil sulphuric acid using Platinum (Pt) electrode the product obtained at anode will be:

    A
    Oxygen gas
    B
    `H_(2)S` gas
    C
    `SO_(2)` gas
    D
    Hydrogen gas
  • On elctrolysis of dil sulphuric acid using Platinum (Pt) electrode the product obtained at anode will be:

    A
    Oxygen gas
    B
    `H_(2)S` gas
    C
    `SO_(2)` gas
    D
    Hydrogen gas
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