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On electrolysis of dilute sulphuric acid...

On electrolysis of dilute sulphuric acid using platinum electrodes, the product obtained at the anode will be

A

hydrogen

B

oxygen is more reactive than nitrogen.

C

hydrogen sulphide

D

sulphur dioxide

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The correct Answer is:
To solve the question regarding the product obtained at the anode during the electrolysis of dilute sulfuric acid using platinum electrodes, we can follow these steps: ### Step-by-Step Solution: 1. **Understanding Electrolysis**: - Electrolysis involves passing an electric current through an electrolyte (in this case, dilute sulfuric acid, H₂SO₄) to induce a chemical reaction. 2. **Identifying the Electrolyte**: - Dilute sulfuric acid dissociates in water to produce hydrogen ions (H⁺) and sulfate ions (SO₄²⁻): \[ \text{H}_2\text{SO}_4 \rightarrow 2\text{H}^+ + \text{SO}_4^{2-} \] 3. **Determining the Electrodes**: - In electrolysis, the anode is the positive electrode where oxidation occurs, and the cathode is the negative electrode where reduction occurs. 4. **Identifying Ions at the Anode**: - At the anode, negatively charged ions (anions) are attracted. In dilute sulfuric acid, the relevant anions are hydroxide ions (OH⁻) from water and sulfate ions (SO₄²⁻). 5. **Comparing Electrode Potentials**: - The discharge of ions at the anode depends on their standard electrode potentials. The hydroxide ion (OH⁻) has a lower discharge potential compared to the sulfate ion (SO₄²⁻), meaning it is preferentially discharged. 6. **Reaction at the Anode**: - When hydroxide ions are discharged, they undergo oxidation to form oxygen gas (O₂): \[ 4\text{OH}^- \rightarrow 2\text{H}_2\text{O} + \text{O}_2 + 4e^- \] - This indicates that oxygen gas is produced at the anode. 7. **Conclusion**: - Therefore, the product obtained at the anode during the electrolysis of dilute sulfuric acid using platinum electrodes is **oxygen gas (O₂)**. ### Final Answer: The product obtained at the anode will be **oxygen gas (O₂)**. ---

To solve the question regarding the product obtained at the anode during the electrolysis of dilute sulfuric acid using platinum electrodes, we can follow these steps: ### Step-by-Step Solution: 1. **Understanding Electrolysis**: - Electrolysis involves passing an electric current through an electrolyte (in this case, dilute sulfuric acid, H₂SO₄) to induce a chemical reaction. 2. **Identifying the Electrolyte**: ...
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DISHA PUBLICATION-THE P-BLOCK ELEMENTS (GROUP 15, 16, 17 & 18)-Exercise
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  2. Oxidation state exhibited by sulphur is

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  3. On electrolysis of dilute sulphuric acid using platinum electrodes, th...

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  4. A gas that cannot be collected over water is.

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  5. Sodium thiosulphate is prepared by

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  6. Which of the following is not oxidized by O(3)?

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  7. Which one of the following compounds is a peroxide?

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  8. Sulphur trioxide can be obtained by which of the following reactions:

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  9. Which of the following does not give oxygen on heating?

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  10. Acidity of diprotic acids in aqueous solutions increases in the order

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  11. In the reaction: 3Br(2)+6OH^(Theta)rarr 5Br^(Theta)+BrO(3)^(Theta)+3H...

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  12. In the case of alkali metals, the covalent character decreases in the ...

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  13. Potassium chlorate on heating with cone H2SO4 gives

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  14. In the manufacture of bromine from sea water the mother liquor contain...

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  15. Which of the following species has four lone..

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  16. Which one is the correct order of the size of the iodine species?

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  17. A one litre flask is full of brown bromine vapours. The intensity of b...

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  18. Which is the best description of the behaviour of bromine in the react...

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  19. Conc. HNO3 reacts with I2 to form:

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  20. For a given alcohol the order of reactivity of halogen acids is :

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