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A solution of urea (mol. Mass 60 g mol^(...

A solution of urea (mol. Mass `60 g mol^(-1)`) boils of `100.18^(@)C` at one one atmospheric pressure. If `k_(f)` and `K_(b)` for water are `1.86` and `0.512 K kg mol^(-1)` respectively, the above solution will freeze at:

A

`-6.54^(@)C`

B

`6.54^(@)C`

C

`0.654^(@)C`

D

`-0.654^(@)C`

Text Solution

Verified by Experts

The correct Answer is:
D

`Delta T_(b)=0.18 , Delta T_(b)=m K_(b)`
`(0.18)/(Delta T_(f))=(mK_(b))/(m K_(f)) , (0.18xx1.86)/(0.512)=Delta T_(f) , Delta T_(f)=0.653`
`T^(+)-T_(s)=0.653 , T_(s)=0-0.653^(@)C , T_(s)=-0.653^(@)C`
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Knowledge Check

  • A solution of urea (mol. Mass 56 g mol ^(-1) ) boils at 100.18^(@)C at the atmospheric pressure. If K_(f) and K_(b) for water are 1.86 and 0.512 K kg mol ^(-1) respectively, the above solution will freeze at

    A
    `0.654^(@)C`
    B
    `-0.654^(@)C`
    C
    `6.54^(@)C`
    D
    `-6.54^(@)C`
  • A solution of urea (mol. Mass "56 g mol"^(-1) ) boils at 100.18^(@)C at the atmospheric pressure. If K_(f) and K_(b) for water are "1.86 and 0.512 K kg mol"^(-1) respectively, the above solution will freeze at

    A
    `-6.54^(@)C`
    B
    `-0.654^(@)C`
    C
    `6.54^(@)C`
    D
    `0.654^(@)C`
  • A solution of urea (molecular mass = 60 g mol^(-1) ) boils at 100.18^(@)C at atmospheric pressure. If K_(f) "and" K_(b) for water are 1.86 and 0.512 K kg mol^(-1) respectively, the above solution will freeze at :

    A
    `0.654^(@)C`
    B
    `-0.654^(@)C`
    C
    `6.54^(@)C`
    D
    `-6.54^(@)C`
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