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If the shortest wavelength of Lyman seri...

If the shortest wavelength of Lyman series of hydrogen atom is x, then the wavelength of first member of Balmer series of hydrogen atom will be

A

`9x//5`

B

`36x//5`

C

`5x//9`

D

`5x//36`

Text Solution

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The correct Answer is:
To solve the problem, we need to find the wavelength of the first member of the Balmer series of the hydrogen atom, given the shortest wavelength of the Lyman series is \( x \). ### Step-by-Step Solution: 1. **Understanding the Lyman Series**: The Lyman series corresponds to transitions where the electron falls to the first energy level (\( n = 1 \)). The shortest wavelength in the Lyman series occurs when the electron transitions from \( n = \infty \) to \( n = 1 \). \[ \frac{1}{\lambda} = RZ^2 \left( \frac{1}{n_1^2} - \frac{1}{n_2^2} \right) \] For the Lyman series: - \( n_1 = 1 \) - \( n_2 = \infty \) Thus, the formula simplifies to: \[ \frac{1}{\lambda} = R \cdot 1^2 \left( \frac{1}{1^2} - 0 \right) = R \] Therefore, the shortest wavelength \( \lambda \) (denoted as \( x \)) is: \[ \lambda = \frac{1}{R} = x \] 2. **Understanding the Balmer Series**: The Balmer series corresponds to transitions where the electron falls to the second energy level (\( n = 2 \)). The first member of the Balmer series occurs when the electron transitions from \( n = 3 \) to \( n = 2 \). For the first member of the Balmer series: - \( n_1 = 2 \) - \( n_2 = 3 \) Using the formula again: \[ \frac{1}{\lambda_2} = RZ^2 \left( \frac{1}{n_1^2} - \frac{1}{n_2^2} \right) \] Substituting the values: \[ \frac{1}{\lambda_2} = R \left( \frac{1}{2^2} - \frac{1}{3^2} \right) = R \left( \frac{1}{4} - \frac{1}{9} \right) \] 3. **Finding a Common Denominator**: To simplify \( \frac{1}{4} - \frac{1}{9} \): The common denominator of 4 and 9 is 36. \[ \frac{1}{4} = \frac{9}{36}, \quad \frac{1}{9} = \frac{4}{36} \] Therefore, \[ \frac{1}{4} - \frac{1}{9} = \frac{9 - 4}{36} = \frac{5}{36} \] Substituting back into the equation for \( \lambda_2 \): \[ \frac{1}{\lambda_2} = R \cdot \frac{5}{36} \] 4. **Finding \( \lambda_2 \)**: Now, we can find \( \lambda_2 \): \[ \lambda_2 = \frac{36}{5R} \] 5. **Relating \( R \) to \( x \)**: Since we know that \( R = \frac{1}{x} \), we can substitute this into the equation: \[ \lambda_2 = \frac{36}{5 \cdot \frac{1}{x}} = \frac{36x}{5} \] ### Final Answer: The wavelength of the first member of the Balmer series of the hydrogen atom is: \[ \lambda_2 = \frac{36x}{5} \]
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Knowledge Check

  • If the shortest wave length of Lyman series of H atom is x , then the wave length of the first line of Balmer series of H atom will be-

    A
    `9x//5`
    B
    `36x//5`
    C
    `5x//9`
    D
    `5x//36`
  • The shortest wavelength of Lyman series of the hydrogen atom is equal to the shortest wavelength of Balmer series of a hydrogen -like atom of atomic number Z. The value of Z is equal to

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    2
    B
    3
    C
    4
    D
    6
  • If the series limit wavelength of Lyman series for the hydrogen atom is 912 Å, then the series limit wavelength for Balmer series of hydrogen atoms is

    A
    912 Å
    B
    912 `xx` 2A
    C
    `912 xx ` 4 Å
    D
    `(912)/(2) A`
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