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NiO is antiferromagnetic. But on heating...

`NiO` is antiferromagnetic. But on heating at `250°C`, it becomes paramagnetic. Why?

Text Solution

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In solid state, the magnetic moments of `NiO` are aligned in such a fashion, such that the net moment is zero. So, NiO is antiferromagnetic.
On heating, the alignment is disturbed. The domains are randomized. `Ni^(2+)` has `d^(8)` configuration with unpaired electrons, hence, exhibits paramagnetism.
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Knowledge Check

  • (A) On heating ferromagnetic or ferrimagnetic substances, they become paramagnetic (R) On heating randomsiation of magnetic domains occurs

    A
    Both (A) and (R) are true and (R) is the correct explanation of (A)
    B
    Both (A) and (R) are true and (R) is not the correct explanation of (A)
    C
    (A) is true but (R) is false
    D
    Both (A) and (R) are false
  • (A): Fe_(3)O_(4) is ferrimagnetic at room temperature but becomes paramagnetic at 850 K (R): The magnetic moments in Fe_(3)O_(4) ale aligned equally in parallel and antiparallel directions which on heating randomise

    A
    Both (A) and (R) are true and (R) is the correct explanation of (A)
    B
    Both (A) and (R) are true and (R) is not the correct explanation of (A)
    C
    (A) is true but (R) is false
    D
    (A) is false but (R ) is true
  • The temperature at which a ferromagnetic material becomes paramagnetic is called

    A
    Neutral temperature
    B
    Curie temperature
    C
    Inversion temperature
    D
    None of these
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