Home
Class 12
CHEMISTRY
F2 has lower bond dissociation enthalpy ...

`F_2` has lower bond dissociation enthalpy than `Cl_2`. Why?

Text Solution

Verified by Experts

Fluorine is expected to have the highest value of bond dissociation energy because it has the smallest size and highest eletronegativity value among halogens. Due to its extremely small size, the repulsions among shared electrons take place which reduces its bond dissociation enthalpy, which is less than that of `Cl_2`.
Promotional Banner

Topper's Solved these Questions

  • THE P-BLOCK ELEMENTS

    U-LIKE SERIES|Exercise SELF ASSESSMENT TEST ( SECTION A)|7 Videos
  • THE P-BLOCK ELEMENTS

    U-LIKE SERIES|Exercise LONG ANSWER QUESTION-I|56 Videos
  • THE D-AND F-BLOCK ELEMENTS

    U-LIKE SERIES|Exercise SELF ASSESSMENT TEST (SECTION A ) MULTIPLE CHOICE QUESTIONS (CHOOSE THE CORRECT OPTION)|7 Videos

Similar Questions

Explore conceptually related problems

(a) H_(2)^(+)and H_(2)^(-) ions have same bond order but H_(2)^(-) ion is more stable. Explain. (b) N_(2) has a greater bond dissociation enthalpy than N_(2)^(+) ion hals more bond dissociation enthalpy than O_(2). Why ? (c ) Can we have ahomonuclear diatomic molecule with all its ground state molecular orbitals full of electrons ? (d) When a magnet is dipped in a jar of liquid oxygen, some oxygen clings to it. Assign reason :

Assertion (A): F, has lower bond dissociation energy than Cl_(2) . Reason (R): Flourine is more electronegative than chlorine.

Give reasons : (i) PCl_(5) is more volatile than PCl_(3) . (ii) O-O bond has lower bond dissociation enthalpy than S-S bond. (iii) F_(2) is stronger oxidising than Cl_(2) .

N_(2)^(+) has greater bond dissociation enthalpy than N_(2) molecule.

What is meant by bond dissociation enthalpy?

Explain why N_(2) has a greater bond dissociation energy than N_(2)^(+) while O_(2) has lesser bond dissociation energy than O_(2)^(+).

i. Arrange the following in decreasing order of bond dissociation enthalpy F_(2) , Cl_(2) , Br_(2) , I_(2) ii. Bi does not form pπ-pπ bonds. Give reason for the observation. iii.Electron gain enthalpy of oxygen is less negative than sulphur. Justify

U-LIKE SERIES-THE P-BLOCK ELEMENTS -LONG ANSWER QUESTION-II
  1. Which allotrope of phosphorus is more reactive and why?

    Text Solution

    |

  2. How the supersonic jet aeroplanes are responsible for the depletion of...

    Text Solution

    |

  3. F2 has lower bond dissociation enthalpy than Cl2. Why?

    Text Solution

    |

  4. Which noble gas is used in filling balloons for meteorological observa...

    Text Solution

    |

  5. Complete the equation : XeF2 + PF5 to

    Text Solution

    |

  6. Account for the following: Helium is used in diving apparatus.

    Text Solution

    |

  7. Account for the following: Fluorine does not exhibit positive oxida...

    Text Solution

    |

  8. Account for the following: Oxygen shows catenation behaviour less t...

    Text Solution

    |

  9. Draw the structures of the following molecules : (i) XeF2 (ii) H2S2...

    Text Solution

    |

  10. Complete the following chemical equations : Cu + HNO3 ( dilute) to

    Text Solution

    |

  11. Complete the following chemical equations : XeF4 + O2F2 to

    Text Solution

    |

  12. Explain the following observations: Phosphorus has greater tendency ...

    Text Solution

    |

  13. Explain the following observations: Oxygen is a gas but sulphur is a...

    Text Solution

    |

  14. Explain the following observations: The halogens are coloured. Why?

    Text Solution

    |

  15. Explain the following: NF3 is an exothermic compound whereas NCl3 i...

    Text Solution

    |

  16. Explain the following: F2 is most reactive of all the four common h...

    Text Solution

    |

  17. Complete the following chemical equations : C + H2SO4 (conc. ) to

    Text Solution

    |

  18. Complete the following chemical equations : P4 + NaOH + H2O to

    Text Solution

    |

  19. Complete the following chemical equations : Cl2 + F2 underset("(exce...

    Text Solution

    |

  20. Account for the following: The acidic strength decreases in the ord...

    Text Solution

    |