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The manganate and permanganate ions arei...

The manganate and permanganate ions are_______________in shape.

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tetrahedral
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Potassium Permanganate

24.Which of the following statement(s) is/are correct regarding manganate and permanganate ions? A) All the pi -bonds in manganate and permanganate are formed by the overlap of "p" -orbitals of oxygen and "d" -orbitals of manganese.B) Manganate ion is paramagnetic due to presence of unpaired electron in "p" orbital.C) Permanganate is diamagnetic but becomes paramagnetic on heating. D) The tetrahedral structure of both manganate and permanganate is due to sp^(3) hybridisation.

Knowledge Check

  • Potassium permanganate is used____________.

    A
    as Baeyer's reagent
    B
    in reduction
    C
    in the tanning of leather
    D
    in the manufacture of pigment
  • The ionic charges of manganate and permanganate ion are respectively

    A
    `-2,-2`
    B
    `-1,-2`
    C
    `-2,-1`
    D
    `-1,-1`
  • The magnitude and permanganate ions are tetrahedral due to

    A
    The `pi`- bonding involves overlap of d-orbitals of oxygen with d-orbitals of manganese.
    B
    The `pi-`bonding involves overlap of p-orbitals of oxygen with d-orbitals of mangenese.
    C
    There is no `pi-` bonding
    D
    The `pi-` bonding involves overlap of p-orbitals of oxygen with p-orbitals of mangenese.
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    Draw the structure of permanganate ion ?

    S_1 : Potassium permanganate decomposes to give potassium manganate at 500k. S_2 : Both permanganate and manganate are tetrahedral and paramagnetic.

    The oxidation of manganate ion to permanganate ion can be done by

    Assertion (A) In the reaction between potassium permanganate and potassium iodide, permanganate ions acts as oxidising agent. Reason ( R) Oxidation state of manganese changes from +2 and +7 during the reaction.

    In the laboratory, manganese (II) salt is oxidised to permanganate ion in aqueous solution by