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The solubility of solid silver chromate....

The solubility of solid silver chromate. `Ag_(2) CrO_(4)` . is determined in three solvents. Substance `K_(sp) ` of `Ag_(2) CrO_(4) = 9 xx 10^(-12)`
(I) pure water (ii) 0.1 M `AgNO_(3) " " `(iii) 0.1 M `Na_(2) CrO_(4)`
Predict the relative solubility of `Ag_(2) CrO_(4)` in the three solvents:

A

I = II = III

B

I `lt ` II `lt `III

C

II = III `lt` I

D

`II lt III lt ` I

Text Solution

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The correct Answer is:
D
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Knowledge Check

  • The solubility of solid silver chromate, Ag_2CrO_4, is determined in three solvents. Substance K_(sp) of Ag_2CrO_4 = 9 xx 10^(-12) (1) pure water (II) 0.1 M AgNO_3 (III) 0.1 M Na _2 CrO_4 Predict the relative solubility of Ag_2CrO_4 . in the three solvents:

    A
    `I = II = III`
    B
    ` I lt II lt III`
    C
    ` II = III lt I`
    D
    `II lt III lt I`
  • The solubility of solid silver chromate, Ag_2CrO_4, is determined in three solvents. Substance K_(sp) of Ag_2CrO_4 = 9 xx 10^(-12) (1) pure water (II) 0.1 M AgNO_3 (III) 0.1 M Na _2 CrO_4 Predict the relative solubility of Ag_2CrO_4 . in the three solvents:

    A
    `I = II = III`
    B
    ` I lt II lt III`
    C
    ` II = III lt I`
    D
    `II lt III lt I`
  • The volume of 0.1 M AgNO_(3) should be added to 10.0 ml of 0.09 M K_(2)CrO_(4) to precipitate all the chromate as Ag_(2)CrO_(4) is

    A
    18 ml
    B
    9 ml
    C
    27 ml
    D
    36 ml
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    Calculate the solubility product of Ag_(2)CrO_(4) at 298k, if the EMF of the concentration cell, Ag, Ag^(+)("solid" Ag_(2)CrO_(4))"//"Ag^(+)(0.1M) , Ag is 0.164 V.

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    To Ag_(2)CrO_(4) solution over its own percipitate CrO_(4)^(2-) ions are added . This results in

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