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What is lanthanoid contraction? What are...

What is lanthanoid contraction? What are the consequences of lanthanold contraction?

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**Step-by-Step Text Solution:** **Step 1: Define Lanthanoid Contraction** Lanthanoid contraction refers to the gradual decrease in the size of the lanthanide series elements as we move from left to right across the series. This phenomenon occurs due to the poor shielding effect of the 4f inner electrons. **Step 2: Explain the Cause of Lanthanoid Contraction** The contraction is primarily caused by the fact that the 4f electrons do not shield the nuclear charge effectively. As a result, as we move from one element to the next in the lanthanide series, the effective nuclear charge experienced by the outer electrons increases, leading to a decrease in atomic and ionic radii. ...
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(a) What is meant by the term lanthanoid contraction ? What is it due to and what consequences does it have on the chemistry of elements following lanthanoids in the periodic table ? (b) Explain the following observations : (i) Cu^(+) ion is unstable in aqueous solutions . (ii) Although Co^(2+) ion appears to be stable , it is easily oxidised to Co^(3+) ion in the presence of a strong ligand. (iii) The E_(Mn^(2+)//Mn)^(@) value for manganese is much more than expected from the trend for other elements in the series.

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NCERT ENGLISH-THE D AND F BLOCK ELEMENTS-Exercise
  1. What may be the stable oxidation state of the transition element with ...

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  2. Name the oxometal anions of the first series of the transition metals ...

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  3. What is lanthanoid contraction? What are the consequences of lanthanol...

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  4. What are the characteristics of th transition elements and why are the...

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  5. In What way is the electronic configuration of the transition elements...

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  6. What are the different oxidation states exhibited by the lanthanoids?

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  7. Explain gives reason. (a) Transition metal and many of their compoun...

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  8. What are interstitial compounds? Why are such compounds well known for...

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  9. How is the variability in oxidation states of transition metals differ...

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  10. Describe the preparation of potassium dichromate from iron chromite or...

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  11. Describe the oxidising action of potassium dichromate and write the io...

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  12. Describe the preparation of potassium permanganate. How does the acidi...

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  13. For (M^(2+))/(M) and (M^(3+))/(M^(2+)) systems the E^(ɵ) values for so...

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  14. Predict which of the followingwill be coloured in aqueous solution? T...

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  15. Compare the stability of +2 oxidation state for the elements of the fi...

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  16. Compare the chemistry of actinoids with that of the lanthanoids with s...

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  17. How would you account for the following: A) Of the d^(4) species Cr^(...

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  18. What is meant by 'disproportionation'? Give two examples of disproport...

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  19. Which metal in the first series of transition metals exhibits+1 oxidat...

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  20. Calculate the number of unpaired electrons in the following gaseous io...

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