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(a)What happens when white phosphorus is...

(a)What happens when white phosphorus is heated with concentrated `NaOH` solution in an inert atmosphere of `CO_(2)`?
(b)Draw the structure of white phosphorus and red phosphorus. Which one of these two types of phosphorus, is more reactive and why ?

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### Step-by-Step Solution: **(a)** When white phosphorus (P₄) is heated with concentrated sodium hydroxide (NaOH) solution in an inert atmosphere of carbon dioxide (CO₂), a chemical reaction occurs that produces phosphine (PH₃) and sodium hypophosphite (NaH₂PO₂). The balanced chemical equation for this reaction is: \[ P_4 + 3 \text{NaOH} + 3 \text{H}_2\text{O} \rightarrow 3 \text{PH}_3 + 3 \text{NaH}_2\text{PO}_2 \] ...
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NCERT ENGLISH-THE P-BLOCK ELEMENTS-EXERCISE
  1. What is the covalence of nitrogen in N2O5?

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  2. Bond angle in PH(4)^(+) is higher than that in PH(3).Why ?

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  3. (a)What happens when white phosphorus is heated with concentrated NaOH...

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  4. What happens when (A)PCl(5) is heated. (B)PCl(5) is reacted with h...

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  5. Write a balanced equation for the hydrolytic reaction of PCl5 in heavy...

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  6. What is the basicity of H(3)PO(4) ?

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  7. What happens when (A)PCl(5) is heated. (B)PCl(5) is reacted with h...

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  8. List the important sources of sulphur.

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  9. Write the order of thermal stability of the hydrides of group 16 eleme...

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  10. Why is H(2)O a liquid and H(2)S a gas?

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  11. Which of the following does not react with oxygen directly? Zn,Ti,Pt,F...

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  12. Complete the following reactions: (i) C(2) H(4) + O(2) to (ii)...

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  13. Why does O3 act as a powerful oxidising agent?

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  14. How is O(3) estimated quantitatively ?

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  15. What happens when sulphur dioxide is passed through an aqueous solutio...

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  16. Comment on the nature of two S–O bonds formed in SO(2) molecule. Are t...

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  17. How is the presence of SO2 detected?

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  18. Mention three areas in which H2SO4 plays an important role.

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  19. Write the conditions to maximise the yield of H2SO4 by contact process...

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  20. Why is K(a(2)) ltlt K(a(1)) for H(2) SO(4) in water ?

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