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Discuss the nature of bonding in the fol...

Discuss the nature of bonding in the following coordination entities on the basis of valence bond theory:
(i). `[Fe(CN)_6]^(4-)`
(ii). `[FeF_6]^(3-)`
(iii). `[Co(C_2O_4)_3]^(3-)`
(iv). `[CoF_6]^(3-)`

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To discuss the nature of bonding in the given coordination entities based on Valence Bond Theory (VBT), we will analyze each compound step by step. ### (i) `[Fe(CN)_6]^(4-)` 1. **Determine the Oxidation State of Iron (Fe)**: - The charge of the complex is -4. - Let the oxidation state of Fe be \( x \). - The cyanide ion (CN^-) has a charge of -1, and there are 6 cyanide ligands. ...
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Among the following, the most stable complex is (i). [Fe(H_2O)_6]^(3+) (ii). [Fe(NH_3)_6]^(3+) (iii). [Fe(C_2O_4)_3]^(3-) (iv). [FeCl_6]^(3-)

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Arrange the following in increasing value of magnetic moments. (i) [Fe(Cn)_6]^(4-) (ii) [Fe(CN)_6]^(3-) (iii) [Cr(NH_3)_6]^(3+) (iv) [Ni(H_2O)_4]^(2+)

Specify the oxidation numbers of the metals in the following coordination entities: (i). [Co(H_2O)(CN)(en)_2]^(2+) (ii). [CoBr_2(en)_2]^(o+) (iii). [PtCl_4]^(2-) (iv). K_3[Fe(CN)_6] (v). [Cr(NH_3)_3Cl_3]

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Give the electronic configuration of the following complexes on the basis of crystal field splitting theory. [CoF_(6)]^(3-), [Fe(CN)_(6)]^(4-) and [Cu(NH_(3))_(6)]^(2+) .

Name of following coordinatin entities and describe their structures : (i) [Fe(CN)_(6)]^(4-) (ii) [Cr(NH_(3))_(4)Cl_(2)]^(+) (iii) [Ni(CN)_(4)]^(2-) [Atomic number Fe = 26 , Cr = 24 , Ni = 28]

Name the following coordination entities and draw the structures of their stereoisomers : (i) [Co(en)_(2)Cl_(2)]^(+) (en = ethane-1,2-diamine (ii) [Cr(C_(2)O_(4))_(3)]^(3-) (iii) [ Co(NH_(3))_(3)Cl_(3)] (Atomic number Cr = 24 , Co = 27)

The magnetic moment of complex given below are in the order: (I) [Ni(CO)_(4)] (II) [Mn(CN)_(6)]^(4-) (III) [Cr(NH_(3))_(6)]^(3+) (IV) [CoF_(6)]^(3-)

NCERT ENGLISH-COORDINATION COMPOUNDS-Exercise
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  2. Aqueous copper sulphate solution (blue in colour) gives: (i). A gree...

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  3. What is the coordination entity formed when excess of aqueous KCN is a...

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  4. Discuss the nature of bonding in the following coordination entities o...

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  5. Draw figure to show the splitting of d orbitals in an octahedral cryst...

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  6. What is spectrochemical series? Explain the difference between a weak ...

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  7. The magnitude of CFSE (Crystal Field Splitting Energy , Delta(0)) can ...

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  8. [Cr(NH3)6]^(3+) is paramagnetic while [Ni(CN)4]^(2-) is diamagnetic. E...

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  9. A solution of [Ni(H(2)O)(6)]^(2+) is green but a solution of [Ni(CN)(4...

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  10. [Fe(CN)(6)]^(4-) and [Fe(H(2)O)(6)]^(2+) are of different colours in d...

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  11. BONDING IN METAL CARBONYLS

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  12. Give the oxidation state, d-orbitals occupation and coordination numbe...

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  13. Wrtie down the IUPAC name for each of the following complexes and indi...

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  14. Explain the violet colour of the complex [Ti(H(2)O)(6)]^(3+) on the ba...

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  15. What is meant by the chelate effect? Give and example.

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  16. Discuss briefly giving an example in each case the role of coordinatio...

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  17. How many ions are produced from the complex Co(NH3)6Cl2 in solution? ...

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  18. Amongst the following ions which one has the highest magnetic moment v...

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  19. Amongst the following, the most stable complex is

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  20. What will be the correct order for the wavelengths of absorption in th...

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