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Molar conductance of electrolytic soluti...

Molar conductance of electrolytic solution `wedge_(m)` is

A

`prop1`

B

`prop(1//A)`

C

`prop(1//C)`

D

`prop(sqrt(C))`

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To solve the question regarding the molar conductance of an electrolytic solution (denoted as \( \Lambda_m \)), we can break down the concept into clear steps. ### Step-by-Step Solution: 1. **Understanding Molar Conductance**: Molar conductance (\( \Lambda_m \)) is defined as the conductance of a solution containing one mole of an electrolyte in a given volume of solution. It is expressed in units of S m²/mol. 2. **Formula for Molar Conductance**: The molar conductance can be calculated using the formula: \[ \Lambda_m = \frac{K \cdot V}{1000} \] where \( K \) is the specific conductance (conductivity) of the solution in S/m, and \( V \) is the volume of the solution in mL. 3. **Relationship with Conductance**: Conductance (\( G \)) is related to the resistivity of the solution. The conductance of a solution can be expressed as: \[ G = \frac{L}{R} \] where \( L \) is the length of the solution path between the electrodes and \( R \) is the resistance of the solution. 4. **Proportionality to Concentration**: Molar conductance is inversely proportional to the concentration of the electrolyte: \[ \Lambda_m \propto \frac{L}{A \cdot C} \] where \( A \) is the cross-sectional area of the electrodes, and \( C \) is the concentration of the solution. 5. **Conclusion**: Therefore, the molar conductance of an electrolytic solution can be expressed in terms of its specific conductance, volume, and concentration. It is a measure of how well the ions in the solution can conduct electricity. ### Final Expression: Thus, the molar conductance \( \Lambda_m \) can be summarized as: \[ \Lambda_m = \frac{K \cdot V}{1000} \quad \text{and} \quad \Lambda_m \propto \frac{L}{A \cdot C} \]

To solve the question regarding the molar conductance of an electrolytic solution (denoted as \( \Lambda_m \)), we can break down the concept into clear steps. ### Step-by-Step Solution: 1. **Understanding Molar Conductance**: Molar conductance (\( \Lambda_m \)) is defined as the conductance of a solution containing one mole of an electrolyte in a given volume of solution. It is expressed in units of S m²/mol. 2. **Formula for Molar Conductance**: ...
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Knowledge Check

  • Conductance of an electrolytic solution depends :

    A
    Nature of electrolyte
    B
    Power of AC source
    C
    Distance between two electrodes
    D
    None of the above.
  • The unit of molar conductance of an electrolyte solution will be

    A
    `ohm^(-1)` cm `mol^(-1)`
    B
    mho `cm^2` `mol^(-1)`
    C
    ohm `cm^(2)` `mol^(-1)`
    D
    `ohm^(-1)` `cm^(-1)` `mol^(-1)`
  • The conductivity of Electrolytic solution depends on-

    A
    Size of the ions produced and their solvation
    B
    The nature of the solvent and its viscosity
    C
    Temperature
    D
    All of the above
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    How does the molar conductance of an electrolyte vary with dilution ?

    Conductivity of an electrolytic solution depends on:

    Assertion : Molar conductance of an electrolyte increases upon dilution. Reason : Ions move faster in dilute solution.

    Statement-1: Specific conductivity of an electrolytic solution decreases with dilution whereas molar conductivity. Statement-2: Specific conductivity is the conductance of a specific amount of the electrolyte whereas molar conductivity is for 1 mole of the electrolyte.

    Assertion Molar conductance of an electrolyte increases with dilution Reason Ions move fast in dilute solutions.