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The hybridisation of chlorine in CIO^(-)...

The hybridisation of chlorine in `CIO^(-), ClO_(2), ClO_(3)^(-)`, and `ClO_(4)^(-)` ions are 

A

`sp^3, sp^3d, sp^3 d^2, sp^3 d^3`

B

`sp^3 d^3, sp^3 d^2, sp^3 d, sp^3`

C

`sp^2, sp^2, sp^2, sp^2`

D

`sp^3, sp^3, sp^3, sp^3`

Text Solution

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The correct Answer is:
D
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Which of the following species, do not show disproportionation reaction and why ? ClO^(-), ClO_(2)^(-), ClO_(3)^(-) and ClO_(4)^(-) Also write reaction for each of the species that disproportionates.

Knowledge Check

  • The number of lone pairs on Chlorine atom in ClO^(-), ClO_(2)^(-), ClO_(3)^(-), ClO_(4)^(-) ions are

    A
    0,1,2,3
    B
    1,2,3,4
    C
    4,3,2,1
    D
    3,2,1,0

  • The number of lone pairs on Chlorine atom in CIO^(-), CIO_(2)^(-), CIO_(3)^(-), ClO_(4)^(-) ions are

    A
    `0,1,2,3`
    B
    `1,2,3,4`
    C
    `4,3,2,1`
    D
    `3,2,1,0`

  • The order of Cl - O bond energy in ClO^(-), ClO_(2)^(-), ClO_(3)^(-), CIO_(4)^(-) is

    A
    `ClO^(-) gt ClO_(2)^(-) gt ClO_(3)^(-) gt ClO_(4)^(-)`
    B
    `ClO_(4)^(-) gt ClO_(3)^(-) gt ClO_(2)^(-) gt ClO^(-)`
    C
    `ClO_(4)^(-) gt ClO_(2)^(-) gt ClO_(3)^(-) gt ClO^(-)`
    D
    `ClO_(3)^(-) gt ClO^(-) gt ClO_(2)^(-) gt ClO_(4)^(-)`

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