Home
Class 12
CHEMISTRY
The boiling point of benzene is 353.23 K...

The boiling point of benzene is 353.23 K. When 1.80 g of a non - volatile solute was dissolved in 90 g of benzene, the boiling point is raised to 354.11 K. Calculate the molar mass of the solute. `K_(b)` for benzene is 2.53 K kg `mol^(-1)`.

Text Solution

Verified by Experts

The elevation `(Delta T_(b))` in the boiling point `= 354.11 K - 353.23 K = 0.88 K`
Sdubstituting these values in expression
`M_(2)=(1000 xx w_(2))xx (K_(b))/(Delta T_(b)xx w_(1))`
we get,
`M_(2)=(2.53"K kg mol"^(-1)xx1.8 g xx1000 g kg^(-1))/(0.88K xx 90 g)`
`= 58 g mol^(-1)`
Therefore, molar mass of the solute,
`M_(2)=58 g mol^(-1)`
Promotional Banner

Topper's Solved these Questions

  • SOLUTIONS

    KUMAR PRAKASHAN|Exercise SECTION - A QUESTIONS|30 Videos
  • SOLUTIONS

    KUMAR PRAKASHAN|Exercise SECTION - A QUESTIONS (SELF - PRACTICE QUESTIONS)|37 Videos
  • SAMPLE QUESTION PAPER

    KUMAR PRAKASHAN|Exercise [PART-B] SECTION - C|2 Videos
  • SURFACE CHEMISTRY

    KUMAR PRAKASHAN|Exercise SECTION - E (MCQs asked in GUJCET/Board Exams)|52 Videos

Similar Questions

Explore conceptually related problems

The vapor pressure of acetone at 20^(@)C is 185 torr. When 1.2 g of a non-volatile solute was dissolved in 100 g of acetone at 20^(@)C , it vapour pressure was 183 torr. The molar mass (g mol^(-1)) of solute is:

A solution containing 0.11kg of barium nitrate in 0.1kg of water boils at 100.46^(@)C . Calculate the degree of ionization of the salt. K_(b) (water) = 0.52 K kg mol^(-1) .

A solution containing 2.5 g of a non-volatile solute in 100 gm of benzene boiled at a temperature 0.42K higher than at the pure solvent boiled. What is the molecular weight of the solute? The molal elevation constant of benzene is "2.67 K kg mol"^(-1) .

The boiling point of benzene at 1 atm is 80.2^@C . Calculate the enthalpy of vaporisation of benzene at its b. pt.

The freezing point of a solution prepared from 1.25 g of non-electrolyte and 20 g of water is 271.9 K . If the molal depression constant is 1.86 K mol^(-1) , then molar mass of the solute will be

The freezing point of ether was lowered by 0.60^(@)C on dissolving 2.0g of phenol in 100g of ether. Calculate the molar mass of phenol and comment on the result. Given: K_(f) (ether) = 5.12 K kg mol^(-1) .

KUMAR PRAKASHAN-SOLUTIONS -SECTION - E MCQs asked in GUJCET/Board Exam
  1. The boiling point of benzene is 353.23 K. When 1.80 g of a non - volat...

    Text Solution

    |

  2. Freezing point of urea solution is -0.6^(0)C. How much urea is require...

    Text Solution

    |

  3. The increase in boiling point of a solution containing 0.6 gram Urea i...

    Text Solution

    |

  4. How many grams of NaOH will be required to Prepare 500 gram solutionco...

    Text Solution

    |

  5. Which of the following aqueous solutions will have maximum osmotic pre...

    Text Solution

    |

  6. If osmotic pressure of a solution at 27^(@)C is 0.82 bar, what will be...

    Text Solution

    |

  7. Which of the following is change with temperature ?

    Text Solution

    |

  8. Which pair is isotonic at same temperature ?

    Text Solution

    |

  9. What is the normality of 0.04 M H(2)SO(4) ?

    Text Solution

    |

  10. Which of the following acts as best semipermeable membrane ?

    Text Solution

    |

  11. The freezing point of the aqueous solution of urea is -0.6^(@)C. How m...

    Text Solution

    |

  12. Find out the osmotic pressure of 0.25 M aqueous solution of Urea at 27...

    Text Solution

    |

  13. Find out normality of the solution prepasred by dissolving 9.8 gram H(...

    Text Solution

    |

  14. The increase in boiling point of a solution containing 0.6 gram Urea i...

    Text Solution

    |

  15. How many grams of NaOH will be required to Prepare 500 gram solutionco...

    Text Solution

    |

  16. The [H(3)O^(+)] concentration in the 200 mL. H(2)SO(4) solution is 1 M...

    Text Solution

    |

  17. Choose the correct statement : When concentration of a salt solution i...

    Text Solution

    |

  18. What is the normality of 250 mL. H(2)SO(4) having pH = 0.0 ?

    Text Solution

    |

  19. When gas is dissolve in liquid solvent and form solution, then accordi...

    Text Solution

    |

  20. Which of the following solution having same vapour pressure as 0.3 M g...

    Text Solution

    |

  21. What will be the normality of 0.2 M H(3)PO(3) solution ?

    Text Solution

    |