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The heating process for the extraction o...

The heating process for the extraction of elements are quite old but highly acceptable method for the extraction of elements. Become in this process the elements produced is in the highly pure state. Mostly `As, Sb,Ni, Zr,B` etc are prepared by this principle 4 mumber of metal sulphides which may be reated first in air to partially convert them to the aride, and then further roasted in the absence of air, wing self reduction.
How does impure Ni is purified

A

impure `Ni+CO_(2) to NiCO_(3) overset(Delta) to NiO+CO_(2) overset(Delta) to Ni(s)`

B

impure `Ni+CO overset(50^(@)C) to Ni(CO)_(3)(g) overset(Delta) to Nis+Co(g) overset("Condensation") to Ni(s)` pure

C

impure `Ni+CO_(2) overset(50^(@)C) toNi(CO)_(4),(s) overset(Delta) toNi(s)+CO(g)`

D

impure `Ni+CO overset(50^(@)C) to Ni(CO)_(4) (g) overset(30^(@)C) to Ni(c) +CO(g)`

Text Solution

Verified by Experts

The correct Answer is:
B

Monds process : Condensation
`underset("1m pure")(Ni)+4CO to Ni(CO)_(4) overset(Delta) to underset(Ni("pure")) underset(dar "condensation")(Ni_(g))+4CO`
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Knowledge Check

  • The heating process for the extraction of elements are quite old but highly acceptable method for the extraction of elements. Become in this process the elements produced is in the highly pure state. Mostly As, Sb,Ni, Zr,B etc are prepared by this principle 4 mumber of metal sulphides which may be reated first in air to partially convert them to the aride, and then further roasted in the absence of air, wing self reduction. For which of the given sulphides auto reduction is applicable

    A
    CuS
    B
    PbS
    C
    HgS
    D
    All
  • The heating process for the extraction of elements are quite old but highly acceptable method for the extraction of elements. Become in this process the elements produced is in the highly pure state. Mostly As, Sb,Ni, Zr,B etc are prepared by this principle 4 mumber of metal sulphides which may be reated first in air to partially convert them to the aride, and then further roasted in the absence of air, wing self reduction. In the purification Zr and Ti, which of the following is/are true

    A
    `Zr+2I_(2) to ZrI_(4) overset("passed over") underset("the white hot w") to` the pure Zr is deposited on W :
    B
    `Ti+2I_(2) to TiI_(4) overset("passed over") underset("the white hot w") to` the pure Ti is deposited on W :
    C
    `Zr+2I_(2) to ZrI_(4) overset("mixed with W") underset("& then heated") to ZrI_(4)` is reudced to `ZrI_(4)`
    D
    Both a & b are correct
  • The heating process for the extraction of elements are quite old but highly acceptable method for the extraction of elements. Become in this process the elements produced is in the highly pure state. Mostly As, Sb,Ni, Zr,B etc are prepared by this principle 4 mumber of metal sulphides which may be reated first in air to partially convert them to the aride, and then further roasted in the absence of air, wing self reduction. The H_(2) (g) is not widely used as a reducing agent because

    A
    `H_(2)` decompose to atomic hydrogen at higher temperature
    B
    `H_(2)` isomerises to orthohydrogen at higher temperature
    C
    many metal form hydrides at lower temperature
    D
    there is also a risk of explosion from hydrogen and dioxygen in air
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