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Compounds which readily undergo hydrolys...

Compounds which readily undergo hydrolysis are

A

`C Cl_(4)`

B

`BCl_(3)`

C

`SiCl_(4)`

D

`CF_(4)`

Text Solution

Verified by Experts

The correct Answer is:
B, C

`BCl_(3)andSiCl_(4)` have vacant orbital of suitable energy to accept a pair of electron from `H_(2)O` molecule and thus easily undergo hydrolysis whereas in `C Cl_(4)andCF_(4)` due to the absence of low lying d - orbitals, hydroysis is not possible
`BCl_(3)+3H_(2)OtoB(OH)_(3)+3HCl`
`SiCl_(4)+4H_(2)OtoH_(4)SiO_(4)+4HCl`
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Knowledge Check

  • Compounds A undergoes hydrolysis to produce a colourless gas with rotten fish smell. The gas gives a vortex ring. The gas is

    A
    `PH_3`
    B
    `P_(2)O_3`
    C
    `P_(2)O_5`
    D
    `P_2S_3`
  • Trihalide which does not undergo hydrolysis easily is

    A
    `NCl_(3)`
    B
    `PCl_(3)`
    C
    `PF_(3)`
    D
    `PBr_(3)`
  • Trihalide which does not undergo hydrolysis easily is

    A
    `NCl_3`
    B
    `PCl_3`
    C
    `PF_3`
    D
    `PBr_3`
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