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A' and 'B' are two isomeric compounds of...

A' and 'B' are two isomeric compounds of the formula `C_(2)H_(5)NO`. 'A' on treatment with P,Os gives 'C'. Both 'A' and 'C' on alkaline hydrolysis evolve `NH_(3)`. 'B' can be easily prepared from acetaldehyde. ‘A' is amphoteric inature and acid derivative.
The structure of ‘A' is

A

`CH_(3)-overset(O)overset(||)C-NH_(2)`

B

`CH_(3)-CH=NOH`

C

`CH_(3)-CH_(2)-N=O`

D

`CH_(3)-overset(O)overset(uarr)N-CH_(3)`

Text Solution

Verified by Experts

The correct Answer is:
D
`CH_(3)-underset((A))overset(O)overset(uarr)N-CH_(3)overset(P_(2)O_(5))to underset(( C ))(CH_(3)-C-=N)to underset((B))(CH_(3)-overset(N-OH)overset(||)CH)`
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Knowledge Check

  • A' and 'B' are two isomeric compounds of the formula C_(2)H_(5)NO . 'A' on treatment with P,Os gives 'C'. Both 'A' and 'C' on alkaline hydrolysis evolve NH_(3) . 'B' can be easily prepared from acetaldehyde. ‘A' is amphoteric inature and acid derivative. 'B' is

    A
    `CH_(3)-CH=NOH`
    B
    `CH_(2)=CH_(2)-NHOH`
    C
    `CH_(2)=CH-CH_(2)NHOH`
    D
    `CH_(3)C-=N`

  • A' and 'B' are two isomeric compounds of the formula C_(2)H_(5)NO . 'A' on treatment with P,Os gives 'C'. Both 'A' and 'C' on alkaline hydrolysis evolve NH_(3) . 'B' can be easily prepared from acetaldehyde. ‘A' is amphoteric inature and acid derivative. 'C' is

    A
    `CH_(3)C-=N`
    B
    `CH_(3)C underset(to)=N`
    C
    `CH_(2)=CH-CN`
    D
    None of these

  • An organic compound with molecular formula C_(3)H_(5)N on hydrolysis gives an acid. The acid on heating with N_(3)H and conc. H_(2)SO_(4) gives

    A
    Propanamide
    B
    Ethyl acetate
    C
    Methyl amine
    D
    Ethyl amine

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