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The magnetic properties of NO(2) and N(2...

The magnetic properties of `NO_(2) and N_(2)O_(4)` are different. Why?

Text Solution

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`NO_(2)` molecule has unpaired electron. Hence it is paramagnetic and reactive. `NO_(2)` dimerises to give `N_(2)O_(4). N_(2)O_(4)` molecule has no unpaired electrons. Hence it is diamagnetic.
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Knowledge Check

  • Some of the properties of the two species, NO_(2)^(-) and H_(3)O^(+) are described below. Which one of them is correct?

    A
    Dissimilar in hybridization for the central atom with different structures.
    B
    Isostructural with same hybridization for the central atom
    C
    Isostructural with different hybridization for the central atom
    D
    Similar in hybridization for the central atom with different structures
  • Vapour density of the equilibrium mixture of NO_(2) and N_(2)O_(4) is found to be 40 for the equilibrium N_(2)O_(4) harr 2NO_(2) . From this information answer the following Percentage of NO_(2) in the mixture is

    A
    `26%`
    B
    `24%`
    C
    `28%`
    D
    `22%`
  • Vapour density of the equilibrium mixture of NO_(2) and N_(2)O_(4) is found to be 40 for the equilibrium N_(2)O_(4) harr 2NO_(2) . From this information answer the following Abnormal molecular weight is

    A
    80
    B
    40
    C
    60
    D
    57.5
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    Compare the relative stability of following species and indicate their magnetic properties : O_2 , O_(2)^(+) ,O_2 ^(-) ,(superoxide), O_(2)^(-2) (peroxide)

    Which is not a property of H_(2)O_(2)

    Mention to which oxyacids N_(2)O, N_(2)O_(4) and N_(2)O_(5) are anhydrides?

    Vapour density of the equilibrium mixture of NO_(2) and N_(2)O_(4) is found to be 40 for the equilibrium N_(2)O_(4) harr 2NO_(2) . From this information answer the following Degree of dissociation of N_(2)O_(4) is

    N_(2)O_(4) harr 2NO_(2), N_(2)O_(4(g)) dissociates until the partial pressures of N_(2)O_(4) and NO_(2) become equal, initial pressure of N_(2)O_(4) is 9 atmosphere. What is K_(P) ?