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Co(NH3)5 Br.SO4, when it is treated wit...

`Co(NH_3)_5 Br.SO_4`, when it is treated with `AgNO_3` gives yellow precipitate, give its structure.

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Knowledge Check

  • AgNO_(3) gives yellow ppt with

    A
    `KIO_(3)`
    B
    KI
    C
    `CHI_(3)`
    D
    `CH_(2)I_(2)`

  • Lassaigne's extract of m-nitrochlorobenzene is acidified with dil. HNO_(3) and then treated with AgNO_(3) solution, the white precipitate formed is due to :

    A
    AgCl
    B
    AgCN
    C
    both (a) and (b)
    D
    `Ag_(2)O`

  • A metal comples having composition Cr(NH_(3))_(4)CI_(2)Br has been isolated in two forms A and B. The form A reacts with AgNO_(3) to give a white precipitate readily soluble in dilute aqueous ammonia, where as B gives a plae yellow precipitate soluble in concentrated ammonia. The hybridisation of Cr in A and magnetic momentum in B are respectively

    A
    `d^(2)sp^(3),2.8BM`
    B
    `sp^(3)d^(2),3.8MB`
    C
    `d^(2)s^(3),3.8BM`
    D
    `sp^(3)d^(2),2.8BM`

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    A solution of white crystals gives a precipitate with AgNO_(3) but no precipitate with a solution of Na_(2)CO_(3) . The action of conc. H_(2)SO_(4) on the crystals yields a brown gas. The crystals are of :

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    Assertion: The complex [Co(NH_3)_3Cl_3] gives no precipitate with AgNO_3 solution Reason: The given complex is non-ionizable

    The compounds that gives white precipitates with AgNO_(3) .

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