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An aqueous solution of a white salt A gi...

An aqueous solution of a white salt A gives a white precipitate B on treatment with dilute HCI in cold conditions. B is soluble in boiling water. An aqueous solution of A gives a yellow precipitate on treatment with a solution of `K_(2)CrO_(4)`. The soda extract of A is acidified with dilute `H_(2)SO_(4)` boiled to remove `CO_(2)` and treated with a freshly prepared solution of `FeSO_(4)` Concentrated `H_(2)SO_(4)` is added to the resulting solution (along the walls of the test tube so that the `H_(2)SO_(4)` forms a separate layer). A brown ring is formed at the junction of the two layers.
On treatment with a Kl solution, an aqueous solution of A will give

A

a yellow precipitate soluble in boiling water

B

a yellow precipitate insoluble in boiling water

C

a white precipitate soluble in boiling water

D

a white precipitate insoluble in boiling water

Text Solution

Verified by Experts

The correct Answer is:
A

Yellow precipitate due `PbI_(2)`
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