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Explain inductive effect...

Explain inductive effect

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Explain mesomeric and inductive effects present in vinyl chloride.

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Knowledge Check

  • (A) : The pKa of the - COOH of alanine is much greater than pKa of -COOH of CH_(3)COOH (R ) : The electron withdrawing inductive effect of N^(+) stabailises the -COOH.

    A
    Both (A) and (R ) are true and (R ) is the correct explanation of (A)
    B
    Both (A) and (R ) are true and (R ) is not the correct explanation of (A)
    C
    (A) is true but (R ) is false
    D
    (A) is false but (R ) is true

  • When an electron withdrawing or electron releasing group is attached to carbon chain, polarity is induced on the carbon atom and on the substituent attach to it. This permanent polarity is due electron displacement due to difference in electronegativities this is called inductive effect or I effect. The inducitve effect depends in the electronegativity of the substituent. The inductive effect is broadly classified as (i) negative inductive effect or -I effect. (ii) positive inductive effect or +I effect. Which of the following statements is correct about inductive effect ?

    A
    Polarization of a `sigma-` bond is called inductive effect.
    B
    Inductive effect is transmitted through `sigma-` bonds
    C
    Inductive effective is transmitted through `pi-` bond
    D
    Both a and b.

  • When an electron withdrawing or electron releasing group is attached to carbon chain, polarity is induced on the carbon atom and on the substituent attach to it. This permanent polarity is due electron displacement due to difference in electronegativities this is called inductive effect or I effect. The inducitve effect depends in the electronegativity of the substituent. The inductive effect is broadly classified as (i) negative inductive effect or -I effect. (ii) positive inductive effect or +I effect. Which of the following statements is correct about inductive effect ?

    A
    Polarization of a `sigma-` bond is called inductive effect.
    B
    Inductive effect is transmitted through `sigma-` bonds
    C
    Inductive effective is transmitted through `pi-` bond
    D
    Both a and b.

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    Explain briefly on the following Inductive effect.

    Mention the inductive effect in monochloro acetic acid.

    What do you understand by inductive effect ? IIIustrate your answer with two examples.

    How is inductive effect useful to explain the relative strength of aliphatic carboxylic acids? Explain with suitable examples.

    Write the differences between inductive effect and mesomeric effect

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