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In the preparation of alkenes, dehydrati...

In the preparation of alkenes, dehydration of alcohols, dehydrohalogenation of alkyl halides, dehalogenation of vicinal dihalides are called `beta`-elimination reactions

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Mention the reagents used in the preparation of alkenes by dehydration, dehydro- halogenation and dehalogenation.

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(A) Ethers are not generally prepared by acid dehydration of 2^@ and 3^@ alcohols (R) dehydration of 29 and 30 alcohols gives alkenes by elimination

Birch reduction : Birch reduction involves controlled reduction of alkynes & atomic compounds in the preseance of alkali metals & alcohol. It provides a method to sterospecifically prepare alkenes of E- configuration R - C -= C -R overset(M,EtOH)to The characteristic type of reaction of alkynes is electrophilic addition reaction like alkenes. The alkynes show various reactions such as halagenation, hydration, hydrogenation etc... 0.40 5g sample of hydrocarbon occupies 229.54ml at 100^(@)C & 1 atm pressure. It decolouses KMnO_4 & Br_2 water. When it reacts with dil. H_2SO_4 under appropriate conditions methyl ethyl, ketone is formed The molecular formula of the hydrocarbon is

AAKASH SERIES-GENERAL ORGANIC CHEMISTRY-Subjective Exercise -8
  1. Nucleophiles are either negatively charged or neutral

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  2. Cl^(-), Br^(-), I^(-), NH(2)^(-) , RNH^(-), R(2)N^(-), OR^(-), RCOO^(-...

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  3. overset(..)(N)H(3), R overset(..)(N)H(2), R(2)NH, R(3) overset(..)(N),...

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  4. Electrophiles are electron deficient and attack the substrate where th...

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  5. Electrophiles are either positively charged or neutral

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  6. H^(+). Cl^(+), Br^(+), I^(+), NO(2)^(+), R(3)C^(+), NH(4)^(+), NO^(+),...

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  7. SO(3), BF(3), AlCl(3), FeCl(3), ZnCl(2), BeCl(2) etc., are neutral ele...

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  8. Nucleophiles act as Lewis bases and electrophiles act as Lewis acids

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  9. Ambiphiles are those species which behave like electrophiles and nucle...

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  10. In substitution reactions, an atom or a group attached to a carbon ato...

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  11. Substitution reactions are further classified as free radical, electro...

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  12. Alkanes undergo free radical substitution, aromatic compounds undergo ...

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  13. If the attaching reagent adds on to the substrate molecule without eli...

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  14. In addition reactions, a triple bond is converted to double bond and a...

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  15. Addition reactions are also of three types: Electrophilic, nucleophili...

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  16. Unsaturated hydrocarbons undergo electrophilic addition and carbonyl c...

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  17. In elimination reactions, generally atoms or groups from adjacent carb...

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  18. In elimination reactions, two sigma bonds are lost are a new pi bond i...

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  19. In the preparation of alkenes, dehydration of alcohols, dehydrohalogen...

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  20. In a molecular rearrangement reaction, the product formed is different...

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