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Arrange the complexes CoCl3. 6NH3, CoCl...

Arrange the complexes `CoCl_3. 6NH_3, CoCl_3. 5NH_3, CoCl_3. 4NH_3` and `CoCl_2 . 3NH_3` in the descending order of conductivity of their aqueous solutions.

Text Solution

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Aqueous solutions containing one mole of `CoCl_(3).6NH_(3), CoCl_(3).5NH_(3),CoCl.4NH_(3)` and `CoCl_(3).3NH_(3)` gives respectively 4, 3, 2 and zero moles of ions. Mbr< Thus the conductivity order is `CoCl_(3).6NH_(3) gt CoCl_(3).5NH_(3) gt CoCl_(3).4NH_(3) gt CoCl_(3).3NH_(3)`.
Aqueous solution of `CoCl_(3).3NH_(3)` does not possess any ions and it is non conductor of electricity. `CoCl_(3).3NH_(3)` is a non electrolyte.
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Arrange the complexes CoCl_3.6NH_3, CoCl_3 .5NH_3, CoCl_3. 4NH_3 and CoCl_3 . 3NH_3 in the descending order of conductivity of their aqueous solutions.

Explain Werner's theory. Give the Werner's structures of CoCl_3. 6NH_3 , CoCl_3 . 5NH_3, CoCl_3 . 4NH_3 and CoCl_3 . 3NH_3 .

Knowledge Check

  • Consider the following complexes 1) K_2PtCl_6 2) PtCl_4 . 2NH_3 3) PtCl_4 . 3NH_3 4) PtCl_4. 5NH_3 Their electrical conducatance in aqueous solutions are

    A
    256, 0, 97 and 404 respectively
    B
    404, 0, 97 and 256 respectively
    C
    256, 97, 0 and 404 respectively
    D
    404, 97, 256 and 0 respectively
  • The number of ions given by [CO(NH_3)_3CI_3] in aqueous solution is

    A
    1
    B
    2
    C
    3
    D
    zero
  • 'B' is a weak basic aqueous NH_(3) solution

    A
    `NH_(4)OH`
    B
    `NH_(4)Cl`
    C
    `NH_(4)NO_(2)`
    D
    `(NH_(4))_(3)PO_(4)`
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