Home
Class 12
CHEMISTRY
The spin only magnetic moment of [MnBr4]...

The spin only magnetic moment of `[MnBr_4]^(2-)` is 5.9BM. Predict the geometry of the complex ion.

Text Solution

Verified by Experts

Since the coordination number of `Mn^(2+)` ion in the complex ion is 4, the geometry may be either tetrahedral `(sp^(3))` or square planar `(dsp^(2))`. But the fact that the magnetic moment of the complex ion is 5.9BM, it should be tetrahedral in shape but not square planar. This is because of the presence of 5 unpaired electrons in the d-orbitals.
Doubtnut Promotions Banner Mobile Dark
|

Similar Questions

Explore conceptually related problems

The spin only magnetic moment of [MrBr_4]^(2-) is 5.9BM. Predict the geometry of the complex ion.

The spin only magnetic tnoment of [MnBr_(4)]^(2-) is 5.9 BM. Predict the geometry of the complex ion ?

Knowledge Check

  • The spin only magnetic moment [Mn(Br)_4]^(2+) is 5.9BM. Then possible hybridisation of Mn in the complex is

    A
    `sp^3d`
    B
    `dsp^2`
    C
    `d^2sp^3`
    D
    `sp^3`
  • The spin-only magnetic moment of an ion is 3.87 BM. The ion is

    A
    `Ti^(2+)`
    B
    `Co^(2+)`
    C
    `Cu^(2+)`
    D
    `Mn^(2+)`
  • Assertion: The spin only magnetic moment of [MnBr_4]^(2-) is 5.9 BM Reason: [MnBr_4]^(2-) is tetrahedral with sp^3 hybridisation of Mn^(2+) having 3d^5 configuration

    A
    Both Assertion & Reason are true ,Reason is the correct explanation of Assertion
    B
    Both Assertion & Reason are true, Reason is not correct explanation of Assertion
    C
    Assertion is true , Reason is false
    D
    Assertion is false , Reason is false
  • Similar Questions

    Explore conceptually related problems

    Calculated spin only magnetic moment of Cr^(x+) is 4.9 BM. Find the 'x' value.

    Calculated spin only magnetic moment of Cr^(x+) is 4.9 BM. Find the 'x' value.

    Calculate the spin only magnetic moment of Ti^(3+) in C.G.S unit

    Calculate the 'spin only' magnetic moment of Fe_(aq)^(2+) ion.

    The spin only magnetic moment of Ni^(2+) in aquous solution would be