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When a metal rod M is dipped into an aqu...

When a metal rod M is dipped into an aqueous colourless concentreted solution ofcompound N, the solution tuns light blue. Addition ofaqueousn NaCI to the blue solution gives a white precipitate 'O'. Addition ofaqueous `NH_3` dissolves 'O' gives an intese blue solution
The metal rod M is

A

Fe

B

Cu

C

Ni

D

Co

Text Solution

Verified by Experts

The correct Answer is:
B

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A gas 'X' is passed through water to form a saturated solution. The aqueous solution on treatment with silver nitrate gives a white precipitate. The saturated aqueous solution also dissolves magnesium ribbon with evolution of a colourless gas 'Y'. Identify 'X' and 'Y':

(i) A white solid A, on being strongly heated, leaves a residue which is yellow while hot and white hot and white when cold ii) The solid A, insoluble in water, dissolves in dilute HCI to give a solution B and a gas which does nor affect acidified dichromate paper but turns baryta water milky. iii) When H_(2)S is passed through the solution B, a white precipitate C is obtained iv) The precipitate C dissolves in dilute HCI to give a solution which, when treated with an NaOH solution, gives a white precipitate. The final precipitate dissolves in an excess of NaoH form a solution D. This alkaline solution, on acidification with acetic acid followed by treatment with H_(2)S , gives the precipitate C. Given that the formation of the precipitate C from the solution D involves the reaction [M(OH)_(4)]^(2-)+4H^(+) to underset(underset(MS darr)(darr H_(2)S))(M^(2+))+4H_(2)O M is

Knowledge Check

  • When a metal rod M is dipped into an aqueous colourless concentreted solution ofcompound N, the solution tuns light blue. Addition ofaqueousn NaCI to the blue solution gives a white precipitate 'O'. Addition ofaqueous NH_3 dissolves 'O' gives an intese blue solution The compund N is

    A
    `AgNO_3`
    B
    `Zn(NO_3)_2`
    C
    `Al(NO_3)_3`
    D
    `Pd(NO_3)_2`
  • When a copper wire is dipped in aqueous AgNO_(3) solution, the solution turns blue. The reason for this is

    A
    Oxidation of silver
    B
    Reduction of copper
    C
    Oxidation of copper
    D
    Reduction of silver
  • A metal nitrate reacts with KI to give a black precipitate which addition of excess of KI converts into orange colour solution. The cation of metal nitrate is:

    A
    `Hg^(2+)`
    B
    `Bi^(3+)`
    C
    `Pb^(2+)`
    D
    `Cu^(+)`
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