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Describe hybridisation in the case of PC...

Describe hybridisation in the case of `PCl_(5) and SF_(6)` The axial bonds are longer as compared to equatorial bonds in `PCl_(5)` whereas in `SF_(6)` both axial bonds and equatorial bonds and have the same bond length. Explain.

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To describe the hybridization in the case of \( PCl_5 \) and \( SF_6 \), and to explain the differences in bond lengths between axial and equatorial bonds in these molecules, we can follow these steps: ### Step 1: Determine the hybridization of \( PCl_5 \) 1. **Identify the central atom**: In \( PCl_5 \), phosphorus (P) is the central atom. 2. **Count the valence electrons**: Phosphorus has 5 valence electrons. Each chlorine (Cl) contributes 1 valence electron, and there are 5 chlorine atoms, contributing a total of 5 electrons. 3. **Calculate the total number of electrons**: \[ ...
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Knowledge Check

  • Assertion : In trigonal bipyramidal structure two axial bonds are longer than the equatorial bonds. Reason : Axial bonds suffer more repulsion as compared to equatorial bonds.

    A
    If both assertion and reason are true and reason is the correct explanation of assertion.
    B
    If both assertion and reason are true but reason is not the correct explanation of assertion.
    C
    If assertion is true but reason is false.
    D
    If both assertion and reason are false.
  • Assertion :-The o-bond is stronger as compared to a pi -bond. Reason :-The axial overlapping of atomic orbitals is much more as compared to their sidewise overlapping.

    A
    If both Assertion and Reason are CORRECT and Reason is the CORRECT explanation of the Assertion
    B
    If both Assertion and Reason are CORRECT but Reason is not the CORRECT explanation of the Assertion.
    C
    If Assertion is CORRECT but Reason is INCORRECT.
    D
    If Assertion is INCORRECT but Reason is CORRECT.
  • Similar Questions

    Explore conceptually related problems

    Number of chlorine atoms which form equatorial bonds in PCl5 molecule are _

    Number of right angle bonds in PCl_(5) is _______.

    Explain the structures of PCl_5 and SF_6 with in the framework of octet rule.

    Explain the bond lengths of all P-Cl bonds in PCl _(5) molecule.

    All possible bond angles in anionic part of PCl_(5) are

    Statement-1 : PCl_(5) has trigonal bipyramidal shape . and Statement-2 : Length of all P-Cl bonds in PCl_(5) is equal