Home
Class 11
CHEMISTRY
An alkane C(8)H(18) is obtained as the o...

An alkane `C_(8)H_(18)` is obtained as the only product on subjectiog a primary alkyl halide to wurtz reaction. On monobromination this alkane yieles a single isomer of a tertiary bromide . Write the structure of alkane and the tertiary bromide.

Text Solution

AI Generated Solution

To solve the problem, we need to identify the alkane \( C_8H_{18} \) that is produced from a primary alkyl halide through the Wurtz reaction and determine the structure of the tertiary bromide formed upon monobromination of this alkane. ### Step-by-Step Solution: 1. **Understanding the Wurtz Reaction**: - The Wurtz reaction involves the coupling of two alkyl halides in the presence of sodium metal, resulting in the formation of a higher alkane. The general reaction doubles the number of carbon atoms. - Since we are given \( C_8H_{18} \), we can infer that the initial alkyl halide must have had 4 carbon atoms, as two molecules of a 4-carbon alkyl halide would combine to form an 8-carbon alkane. ...
Promotional Banner

Topper's Solved these Questions

  • HYDROCARBONS

    NCERT EXEMPLAR ENGLISH|Exercise Matching The Columns|4 Videos
  • HYDROCARBONS

    NCERT EXEMPLAR ENGLISH|Exercise Assertion and Reason|4 Videos
  • HYDROCARBONS

    NCERT EXEMPLAR ENGLISH|Exercise Multiple Choice Questions (More Than One Options)|9 Videos
  • ENVIRONMENTAL CHEMISTRY

    NCERT EXEMPLAR ENGLISH|Exercise Long Answer Type|5 Videos
  • HYDROGEN

    NCERT EXEMPLAR ENGLISH|Exercise LONG ANSWER TYPE QUESTIONS|8 Videos

Similar Questions

Explore conceptually related problems

Which alkane would have only the primary and tertiary carbon ?

Which alkane cannot be be produced using only one type of alkyl halide in Wurtz reaction?

Which of the following alkane is synthesised from single alkyl halide by wurtz reaction:-

An alkane C_(7)H_(16) is produced by the reaction of lithium di(3-pentyl)cuprate with ethyl bromide. The name of the product is

There are five isomeric alkenes (A, B, C, D, and E) that require 1 mol of H_(2) per mole of alkene for hydrogenation and give the same product (F) on hydrogenation. F is an alkane having the lowest molecular mass and is opticalar mass and is optically active. Write the structures of the compounds from A to F.

There are six isomeric alkenes (A, B, C, D, E, and F) that require 1 mol of H_(2) per mole of alkene for hydrogenation and give the same product (G) on hydrogenation. G is an alkane having the lowest molecular mass and is optically active. Write the structure of compounds from A to G.

A compound of molecular formula C_(8)H_(8)O_(2) reacts with acetophenone is form a single cross-aldol product in the presence of base. The same compound on reaction with conc. NaOH forms benzyl alcohol as one of the products. The structure of the compounds is :

Explain the following observations: (a) Azide ion (N_(3)) react with 2- bromopentane thousand times faster than with neopentyl bromide in a S_(N)2 reaction through former is a secondary halide while latter is primary. (b) What will happen to the stereochemistry of product of the following reaction: (c) What will happens to the rate if the concentration of alkyl bromide in (b) is doubled? (d) Wha will happen to the rate if the concentration of azide ion in (b) is doubled? (e) How the sign of optical rotation of reactant and product are related in (b) (f) When allowed to stand in dilute H_(2)SO_(4) laevo-rotatory 2-butanol slowly loss optical activity.

When boromobenze is monochlorinated. Two isomeric compounds (A) and (B) are obtained. Monobromination of (A) gives several isomeric products of molecular formula C_(6) H_(3)ClBr_(2) . While mononbromination of (B) yields only two isomers (C) and (D) . Compound (C) is identiacla to one of the compounds obtained from the bromination of (A) . However, (D) is totally different form any of the isomeric compounds obtained from the bromination of (A) . Give the sturctures of (A),(B),(C) and (D) , and also the structers of the four isomeric mononbrominated products of (A) . Support your answer wtih resoning.

Compound 'A' with molecular formula C_(4)H_(9) Br is treated with aq. KOH solution. The rate of this reaction depends upon the the concentration of the compounds 'A' only. When another optically active isomer 'B' of this compound was treated with aq. KOH solution, the rate of reaction was found to be dependent on concentration of compound and KOH both. (i) Write down the structural formula of both compounds 'A' and 'B'. (ii) Out of these two compounds, which one will be converted to the product with inverted configuration.

NCERT EXEMPLAR ENGLISH-HYDROCARBONS-Short Answer Type Questions
  1. Why do alkenes prefer to undergo electrophilec addition reaction while...

    Text Solution

    |

  2. Alkynes on reduction with sodium in liquid ammonia form trans alkenes....

    Text Solution

    |

  3. Rotation around carbon-carbon single bond of ethane is not completely ...

    Text Solution

    |

  4. Draw Newman and sawhorse projections for the eclipsed and staggered co...

    Text Solution

    |

  5. The intermediate carbocation formed in the reactions of HI,HBr, and HC...

    Text Solution

    |

  6. What will be the product obtain as a result of the following reaction?

    Text Solution

    |

  7. How will you convert benzene into (a) p-nitrobromobenzene (b) m-nitrob...

    Text Solution

    |

  8. Arrange the following set of compounds in the order of their decreasin...

    Text Solution

    |

  9. Despite their-I effect, halogens are o- and p- directing in haloarenes...

    Text Solution

    |

  10. Why does presence of a nifro group make the benzene ring less reactive...

    Text Solution

    |

  11. Suggest a route for the preparation of nitrobenzene starting from acet...

    Text Solution

    |

  12. Predict the major product(S) of the following reactions and explain th...

    Text Solution

    |

  13. Nucleophiles and electrophiles are reaction intermediates having elect...

    Text Solution

    |

  14. The relative reactivity of 1^(@), 2^(@) and 3^(@) hybrogen's towards c...

    Text Solution

    |

  15. Write the structures and names of products obtained in the reactions o...

    Text Solution

    |

  16. Write hydrocarbon radicals that can be formed as intermediates during ...

    Text Solution

    |

  17. An alkane C(8)H(18) is obtained as the only product on subjectiog a pr...

    Text Solution

    |

  18. The ring systems having following characteristics are aromatic. (i) ...

    Text Solution

    |

  19. Which of the following compounds are aromatic according to Huckel's ru...

    Text Solution

    |

  20. Suggest a route to prepare ethyl hydrogensulphate (CH(3)-CH(2)-OSO(2)-...

    Text Solution

    |