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E(cell)^(@) for the given redox reaction...

`E_(cell)^(@)` for the given redox reaction is 2.71 V
`Mg_((s))+Cu_((0.01 M))^(2+)toMg_((0.001 M))^(2+)+Cu_((s))`
Calculate `E_(cell)` for the reaction. Write the direction of flow of current when an external opposite potential applied is
(i) less than 2.71 V and (ii) greater than 2.71 V.

Text Solution

AI Generated Solution

To calculate the cell potential \( E_{cell} \) for the given redox reaction, we will use the Nernst equation. The reaction provided is: \[ \text{Mg}_{(s)} + \text{Cu}^{2+}_{(0.01 M)} \rightarrow \text{Mg}^{2+}_{(0.001 M)} + \text{Cu}_{(s)} \] ### Step 1: Identify the standard cell potential \( E^\circ_{cell} \) The standard cell potential \( E^\circ_{cell} \) is given as 2.71 V. ### Step 2: Write the Nernst equation ...
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Knowledge Check

  • In a cell reaction, Cu_((s))+ 2Ag_((aq))^(+) to Cu_((aq))^(2+) + 2Ag_((s)) E_"cell"^@ =+0.46 V . If the concentration of Cu^(2+) ions is doubled then E_"cell"^@ will be

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