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Glucose and galactose differs on which c...

Glucose and galactose differs on which carbon atom.

A

`2^(nd)` carbon atom

B

`3^(rd)` carbon atom

C

`4^(th)` carbon atom

D

`5^(th)` carbon atom

Text Solution

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The correct Answer is:
To determine the carbon atom at which glucose and galactose differ, we can follow these steps: ### Step 1: Draw the structure of glucose. - Glucose is an aldohexose, meaning it has an aldehyde group at one end and six carbon atoms. The structure can be represented as follows: - C1: CHO (aldehyde group) - C2: CH2OH - C3: CH(OH) - C4: CH(OH) - C5: CH2OH - C6: CH3 (if in the cyclic form, it will be a ring structure) ### Step 2: Draw the structure of galactose. - Galactose is also an aldohexose and has the same molecular formula as glucose but differs in the arrangement of hydroxyl (OH) groups. The structure can be represented as follows: - C1: CHO (aldehyde group) - C2: CH2OH - C3: CH(OH) - C4: CH(OH) - C5: CH2OH - C6: CH3 (if in the cyclic form, it will be a ring structure) ### Step 3: Identify the carbon atoms. - For both glucose and galactose, we can label the carbon atoms from the aldehyde group: - C1: Aldehyde carbon - C2: Second carbon - C3: Third carbon - C4: Fourth carbon - C5: Fifth carbon - C6: Sixth carbon ### Step 4: Compare the structures of glucose and galactose. - When we compare the structures of glucose and galactose, we notice that the hydroxyl (OH) group on the fourth carbon (C4) is positioned differently: - In glucose, the OH group on C4 is on the right side. - In galactose, the OH group on C4 is on the left side. ### Step 5: Conclude the difference. - Therefore, glucose and galactose differ at the fourth carbon atom (C4). This type of difference is known as an epimeric difference, specifically C4 epimers. ### Final Answer: Glucose and galactose differ at the **4th carbon atom**. ---
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Knowledge Check

  • Glucose and galactose differ in configuration at:

    A
    C–1
    B
    C-2
    C
    C-3
    D
    C-4
  • Following are the structure of D-Glucose and D-Galactose. Which of the following statements are correct about these compounds?

    A
    They are diastereomers
    B
    Both are component of lactose
    C
    They are C—4 epimer
    D
    Both are optically active
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