Home
Class 12
CHEMISTRY
The ratio of the shortest wavelength of ...

The ratio of the shortest wavelength of two spectral series of hydrogen spectrum is found to be about 9. The spectral series are:

A

Lymann and Paschen

B

Balmer and Brackett

C

Brackett and Pfund

D

Paschen and Pfund

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem of finding the ratio of the shortest wavelengths of two spectral series of the hydrogen spectrum, we will use the Rydberg formula. The Rydberg formula for the wavelengths of spectral lines in hydrogen is given by: \[ \frac{1}{\lambda} = R_H \left( \frac{1}{n_1^2} - \frac{1}{n_2^2} \right) \] where: - \( \lambda \) is the wavelength, - \( R_H \) is the Rydberg constant, - \( n_1 \) is the principal quantum number of the lower energy level, - \( n_2 \) is the principal quantum number of the higher energy level. ### Step 1: Identify the series and their quantum numbers The spectral series of hydrogen include: - Lyman series: \( n_1 = 1 \) - Balmer series: \( n_1 = 2 \) - Paschen series: \( n_1 = 3 \) - Brackett series: \( n_1 = 4 \) - Pfund series: \( n_1 = 5 \) For the shortest wavelength in each series, \( n_2 \) approaches infinity (\( n_2 \to \infty \)). ### Step 2: Calculate the shortest wavelengths for Lyman and Paschen series 1. **Lyman Series**: - For Lyman, \( n_1 = 1 \) and \( n_2 = \infty \): \[ \frac{1}{\lambda_L} = R_H \left( \frac{1}{1^2} - \frac{1}{\infty^2} \right) = R_H \left( 1 - 0 \right) = R_H \] Thus, \( \lambda_L = \frac{1}{R_H} \). 2. **Paschen Series**: - For Paschen, \( n_1 = 3 \) and \( n_2 = \infty \): \[ \frac{1}{\lambda_P} = R_H \left( \frac{1}{3^2} - \frac{1}{\infty^2} \right) = R_H \left( \frac{1}{9} - 0 \right) = \frac{R_H}{9} \] Thus, \( \lambda_P = \frac{9}{R_H} \). ### Step 3: Find the ratio of the wavelengths Now, we can find the ratio of the shortest wavelengths of the Lyman and Paschen series: \[ \frac{\lambda_L}{\lambda_P} = \frac{\frac{1}{R_H}}{\frac{9}{R_H}} = \frac{1}{9} \] ### Step 4: Invert the ratio to find the ratio of the wavelengths Since the problem states the ratio of the shortest wavelengths, we take the reciprocal: \[ \frac{\lambda_P}{\lambda_L} = 9 \] ### Conclusion The ratio of the shortest wavelengths of the Lyman series to the Paschen series is 9. Therefore, the spectral series are Lyman and Paschen.
Doubtnut Promotions Banner Mobile Dark
|

Topper's Solved these Questions

  • JEE MAINS

    JEE MAINS PREVIOUS YEAR ENGLISH|Exercise QUESTION|1 Videos
  • JEE MAIN

    JEE MAINS PREVIOUS YEAR ENGLISH|Exercise CHEMISTRY|146 Videos
  • JEE MAINS 2020

    JEE MAINS PREVIOUS YEAR ENGLISH|Exercise CHEMSITRY|23 Videos

Similar Questions

Explore conceptually related problems

The ratio of te shortest wavelength of two spectral series of hydrogen spectrum is found to be about 9. The spectral series are:

The ratio of the largest to shortest wavelength in Balmer series of hydrogen spectra is,

Knowledge Check

  • Which one of the series of hydrogen spectrum is in the visible region ?

    A
    Lyman
    B
    Balmer
    C
    Paschen
    D
    Brackett
  • Similar Questions

    Explore conceptually related problems

    The ratio of the longest to shortest wavelength in Brackett series of hydrogen spectra is

    The shortest wavelength of Balmer series of H-atom is

    Number of spectral lines in hydrogen atom is

    Find longest wavelength in Lyman series of hydrogen atom spectrum

    Find wavelength of 1^(st) line of Paschen series of hydrogen spectrum.

    What would be maximum wavelength for Brackett series of hydrogen-spectrum?

    Which one of the series of hydrogen spectrum is in the visible region ?