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The alkene that exhibits geometrical iso...

The alkene that exhibits geometrical isomerism is

A

propene

B

2-methyl propene

C

2-butene

D

2-methyl-2-butene

Text Solution

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The correct Answer is:
To determine which alkene exhibits geometrical isomerism, we need to analyze each option based on the structural requirements for geometrical (cis-trans) isomerism. Geometrical isomerism occurs when there is a double bond between two carbon atoms, and each carbon atom of the double bond must have two different substituents. ### Step-by-Step Solution: 1. **Analyze Option A: Propene** - Structure: Propene (C3H6) has the structure CH2=CH-CH3. - Check the double bond: The double bond is between the first and second carbon atoms. - Substituents: The first carbon (C1) has two hydrogen atoms (H) and the second carbon (C2) has one hydrogen and one methyl group (CH3). - Conclusion: Since C1 has two identical substituents (H), propene cannot exhibit geometrical isomerism. 2. **Analyze Option B: 2-Methylpropene** - Structure: 2-Methylpropene (C4H8) has the structure CH2=C(CH3)-CH3. - Check the double bond: The double bond is between the first carbon (C1) and the second carbon (C2). - Substituents: C1 has two hydrogen atoms (H) and C2 has two methyl groups (C). - Conclusion: Since C1 has two identical substituents (H) and C2 has two identical substituents (C), 2-methylpropene cannot exhibit geometrical isomerism. 3. **Analyze Option C: 2-Butene** - Structure: 2-Butene (C4H8) has the structure CH3-CH=CH-CH3. - Check the double bond: The double bond is between the second carbon (C2) and the third carbon (C3). - Substituents: C2 has one methyl group (CH3) and one hydrogen (H), while C3 also has one methyl group (CH3) and one hydrogen (H). - Conclusion: Both C2 and C3 have different substituents (H and CH3), allowing for the possibility of cis (same side) and trans (opposite side) configurations. Thus, 2-butene can exhibit geometrical isomerism. 4. **Analyze Option D: 2-Methyl-2-butene** - Structure: 2-Methyl-2-butene (C5H10) has the structure CH3-C(CH3)=CH-CH3. - Check the double bond: The double bond is between C2 and C3. - Substituents: C2 has two methyl groups (C) and C3 has one methyl group (C) and one hydrogen (H). - Conclusion: Since C2 has two identical substituents (C), 2-methyl-2-butene cannot exhibit geometrical isomerism. ### Final Answer: The alkene that exhibits geometrical isomerism is **Option C: 2-butene**.
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Knowledge Check

  • Geometrical isomerism is caused

    A
    by restricted rotation around C=C bond
    B
    by the presence of one asymmetric carbon atom
    C
    due to the differennt groups attached to the same functional group
    D
    by swing of hydrogenn atom between two divalent atoms.
  • Which of the following types of compounds is unable to exhibit geometrical isomerism ?

    A
    abc = Cab
    B
    axC = Cay
    C
    aaC = Cab
    D
    none of these
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