In a hydrogen like atom electron make transition from an energy level with quantum number `n` to another with quantum number `(n - 1)` if `n gtgt1` , the frequency of radiation emitted is proportional to :
A
`(1)/(n^(2))`
B
`(1)/(n^(3//2))`
C
`(1)/(n^(3))`
D
`(1)/(n)`
Text Solution
AI Generated Solution
The correct Answer is:
To solve the problem, we need to determine how the frequency of radiation emitted during an electron transition in a hydrogen-like atom is related to the principal quantum number \( n \).
### Step-by-Step Solution:
1. **Understanding the Energy Levels**:
In a hydrogen-like atom, the energy of an electron in a given energy level \( n \) is given by the formula:
\[
E_n \propto -\frac{Z^2}{n^2}
\]
where \( Z \) is the atomic number (for hydrogen, \( Z = 1 \)).
2. **Energy Change During Transition**:
When an electron transitions from an energy level \( n \) to \( n-1 \), the change in energy \( \Delta E \) can be expressed as:
\[
\Delta E = E_n - E_{n-1}
\]
3. **Calculating the Energies**:
Using the energy formula, we can write:
\[
E_n \propto -\frac{1}{n^2} \quad \text{and} \quad E_{n-1} \propto -\frac{1}{(n-1)^2}
\]
4. **Finding the Change in Energy**:
The change in energy \( \Delta E \) can be calculated as:
\[
\Delta E \propto -\frac{1}{n^2} + \frac{1}{(n-1)^2}
\]
Simplifying this expression:
\[
\Delta E \propto \left( \frac{(n-1)^2 - n^2}{n^2(n-1)^2} \right)
\]
\[
= \frac{(n^2 - 2n + 1) - n^2}{n^2(n-1)^2} = \frac{-2n + 1}{n^2(n-1)^2}
\]
5. **Considering \( n \gg 1 \)**:
Since \( n \) is very large, we can approximate:
\[
\Delta E \approx \frac{-2n}{n^2(n-1)^2} \approx \frac{-2}{n^3}
\]
6. **Relating Energy to Frequency**:
The energy emitted during the transition is also related to the frequency \( f \) of the emitted radiation by Planck's equation:
\[
\Delta E = h f
\]
Therefore, we can write:
\[
f \propto \Delta E
\]
7. **Final Relationship**:
Since we found that \( \Delta E \propto \frac{1}{n^3} \), we can conclude that:
\[
f \propto \frac{1}{n^3}
\]
### Conclusion:
The frequency of radiation emitted when an electron transitions from energy level \( n \) to \( n-1 \) in a hydrogen-like atom is proportional to \( \frac{1}{n^3} \).
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