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Explain d orbital ....

Explain d orbital .

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d orbital : d orbital exist in energy level n=3 ,4 5… but in n=1 ,2 orbital d orbital is not exist so 1 and 2 d not exist
not of d orbitals no of orbits = (2l + 1) for d orbital l=2 so no of d orbitals are five (5) so d sub shell has five orbitals
No of d orbitals : for d orbitals l=2 and magnetic quantum number `m_(1) = - 2 ,-1 ,0, +1`
Shape of d orbitals : four d orbitals have same shape with four lobes So `d_(xy) d_(yz)` and `d_(zx)` have lobes in their xy, yz , zx plane which for `d_(x)^(2) ` the lobes are on the x and y axes.
Shape of `d_(x )` orbital is different form other in which two lobes around 2 axis .

Energy of d orbital : In any one sub shell the energy of all five d orbitals is same and equivalent their shape and size also same it the principal quantum number increase and size and energy also increase and size energy also increase 3d `lt 4d lt 5d`
Radial node and Angular node : where the lobes combine there electron density is zero in d orbitals angular node is l and radial node is (n-1-1)
for 3d orbital node (n-1) =3 -2 -1=0
Angular node 1=2
For 3d orbital total nodes = n- 1=3 -1=2 nodes.
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Knowledge Check

  • The angular m om entum of electron in ‘d ’ orbital is equal to

    A
    0h
    B
    `sqrt(6)` h
    C
    `sqrt(2)` h
    D
    `2sqrt(2)` h
  • Which of the following pairs of d-orbitals will have electron density along the axes ?

    A
    `d_(z)^(2),d_(xy)`
    B
    `d_(xy)^(2),d_(yz)`
    C
    `d_(z)^(2),d_(x^(2)-y^(2))`
    D
    `d_(xy)^(2),d_(x^(2)-y^(2))`
  • Which of the following element having one electron in 5d orbital in its electronic configuration ?

    A
    Pm
    B
    Tb
    C
    Nd
    D
    Gd
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