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Calculate the ionisation energy of hydro...

Calculate the ionisation energy of hydrogen atom as well as energy needed to promote its electron from first energy level to third energy level

Text Solution

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Ionization enthalpy n=5
for ionization n`=prop =n_(f )`
in initial electron is in n=5 so `n_(i) =5 ` hydrogen
z=1
`Delta E = 2.18 xx 10^(18) ((1)/(n_(1)^(2) ) - (1)/(n_(f )^(2)))= IE_(5)`
`=2.18 xx 10^(18) ((1)/(5^(2)) - (1)/(prop^(2)))`
`=(2.18 xx 10^(18))/( 25) J`
ti balance ionisation enthalpy of `IE_(5) ` and `IE_(1)` :
`(1E_(5))/( 1E_(1)) = (8.72 xx 10^(20)J )/( 2.18 xx 10^(18) J) = 4.-036 xx 10^(2) = 0.04`
ionization enthalpy of n=1 compare to n=5 is 0.04
for `n_(5)` less and `n_(1)` more ionization enthalpy
`IE(5) : IE (1)`
`=0.04 :1`
`4: 100`
`1: 25`
So IE (1) is approx 25 time more than 1E(5 )`
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