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Discuss the hydrolysis of (a) CH3 COONa...

Discuss the hydrolysis of (a) `CH_3 COONa (b) NH_4`Br and (c) `CH_3 COONH_4`

Answer

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Compare the acidic character between the pairs : a) CH_2 FCOOH or CH_2 Cl COOH b) CH_3 COOH or CH_2F COOH c) CH_3 COOH or CH_3 CH_2 COOH d) F_3 C (C_6H_4) COOH or H_3C(C_6H_4) COOH

Aqueous solution of CH_(3) COONa is basic explain.

Knowledge Check

  • The hydrolysis constant of CH_3 COONa is given by

    A
    `K_b =(K_W)/(K_a) `
    B
    ` K_b = ( K_W)/(K_b) `
    C
    ` K_h= (K_W)/(K_a, K_b) `
    D
    ` K_h =K_a//K_b`

  • A buffer solution is prepared by mixing CH_(3) COONa and CH_(3) COOH . The pK_(a) of acetic acid is 4.74 . To maintain the pH of the buffer solution as 6.04 , the concentration ratio of CH_(3) COONa and CH_(3) COOH to be maintained is

    A
    `1 : 20`
    B
    `1 : 10`
    C
    `2 : 1`
    D
    `20 : 1`

  • What are A, B , C and D in the following reactions ? CH_3 COOH overset(LiAlH_4//(C_2H_5)_2O)toA CH_3 COONa underset(Delta)overset(NaOH//CaO) to B CH_3COOH overset(P_2O_5//Delta)toC CH_3 COOH underset(Delta)overset(NH_3)to D

    A
    `A - CH_3 CHO , B - CH_3 CH_3 , C - (CH_3CO)_2 O, D - CH_3 COONH_4`
    B
    `A - CH_3CH_2 OH, B - CH_4 , C - (CH_3 CO)_2O , D - CH_3 CONH_2`
    C
    `A - CH_3 CH_2 OH, B - CH_3CH_3 , C - (CH_3 CO)_2 O, D -CH_3 CONH_2`
    D
    `A - CH_3 CHO , B - CH_3COCH_3 , C - CH_3OCH_3, D - CH_3 COONH_4`

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    Which one in each of the following pairs is expected exhibit hydrogen bonding together? a. CH_(3)-CH_(2)-OH and CH_(3)-O-CH_(3) b. CH_(3)NH_(2) and CH_(3)SH c. CH_(3)OCH and (CH_(3))_(3)N

    Assign priority number to each of the following groups: (a) -CHO, -OH, -CH_(3), -CH_(2)OH (b) -CH = CH_(2), -CH_(2)CH_(3), - C_(6)H_(5), -CH_(3) (c ) (CH_(3))_(2)CH-,CI-,-CH_(2)CH_(2)Br

    K_a for CH_3 COOH and HCN are respectively 1.8 xx 10^(-5) and 5 xx 10^(-10) Calculate the equilibrium constant for the reaction CH_3 COOH + NaCN hArr CH_3 COONa + HCN .

    Locate the salts undergoing hydrolysis and give the pH values for aqueous NaCl, NH_4 CI, AICI_3 and CH_3 COOK.

    Write the common names of the following halides (a) CH_(3)-CH-CH_(2)Br b) CH_(3)CH_(2)CHCl_(2) c) CH_(2)-overset(I)overset(|)underset(I)underset(|)C-CH_(3) (d) CHBr_(3) e) C Cl_(4)

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