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A hydrogen atom initially in the ground ...

A hydrogen atom initially in the ground level absorbs a photon and is excited to `n=4` level then the wavelength of photon is

A

`790 Å`

B

`870 Å`

C

`970 Å`

D

`1070 Å`

Text Solution

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The correct Answer is:
To find the wavelength of the photon absorbed by a hydrogen atom to excite it from the ground state (n=1) to the n=4 level, we can use the Rydberg formula for hydrogen: \[ \frac{1}{\lambda} = R \left( \frac{1}{n_1^2} - \frac{1}{n_2^2} \right) \] Where: - \( \lambda \) is the wavelength of the emitted or absorbed photon, - \( R \) is the Rydberg constant (\( R \approx 1.097 \times 10^7 \, \text{m}^{-1} \)), - \( n_1 \) is the lower energy level (initial state), - \( n_2 \) is the higher energy level (final state). ### Step-by-step Solution: 1. **Identify the initial and final energy levels**: - The hydrogen atom starts at the ground state, so \( n_1 = 1 \). - The atom is excited to the \( n=4 \) level, so \( n_2 = 4 \). 2. **Substitute the values into the Rydberg formula**: \[ \frac{1}{\lambda} = R \left( \frac{1}{1^2} - \frac{1}{4^2} \right) \] 3. **Calculate the terms**: - \( \frac{1}{1^2} = 1 \) - \( \frac{1}{4^2} = \frac{1}{16} \) 4. **Combine the fractions**: \[ \frac{1}{\lambda} = R \left( 1 - \frac{1}{16} \right) = R \left( \frac{16}{16} - \frac{1}{16} \right) = R \left( \frac{15}{16} \right) \] 5. **Substitute the value of R**: \[ \frac{1}{\lambda} = R \cdot \frac{15}{16} = 1.097 \times 10^7 \cdot \frac{15}{16} \] 6. **Calculate \( \frac{1}{\lambda} \)**: \[ \frac{1}{\lambda} = 1.097 \times 10^7 \cdot \frac{15}{16} = 1.097 \times 10^7 \cdot 0.9375 \approx 1.028 \times 10^7 \, \text{m}^{-1} \] 7. **Find \( \lambda \)**: \[ \lambda = \frac{1}{1.028 \times 10^7} \approx 9.73 \times 10^{-8} \, \text{m} \] 8. **Convert to Angstroms**: - Since \( 1 \, \text{m} = 10^{10} \, \text{Å} \): \[ \lambda \approx 9.73 \times 10^{-8} \, \text{m} \times 10^{10} \, \text{Å/m} \approx 973 \, \text{Å} \] ### Final Answer: The wavelength of the photon absorbed by the hydrogen atom is approximately \( 970 \, \text{Å} \).

To find the wavelength of the photon absorbed by a hydrogen atom to excite it from the ground state (n=1) to the n=4 level, we can use the Rydberg formula for hydrogen: \[ \frac{1}{\lambda} = R \left( \frac{1}{n_1^2} - \frac{1}{n_2^2} \right) \] Where: - \( \lambda \) is the wavelength of the emitted or absorbed photon, ...
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