Home
Class 12
CHEMISTRY
KMnO(4) acts as on oxidising agent in al...

`KMnO_(4)` acts as on oxidising agent in alkaline medium. When alkaline `KMnO_(4)` is treated with `KI`, iodide ion is oxidised to `…………….`

A

`I_2`

B

`IO^(-)`

C

`IO_3^(-)`

D

`IO_4^(-)`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the oxidation of iodide ions by alkaline KMnO4, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Reactants**: The reactants in this reaction are potassium permanganate (KMnO4) and potassium iodide (KI) in an alkaline medium. 2. **Understand the Role of KMnO4**: KMnO4 is known to act as a strong oxidizing agent, especially in alkaline conditions. In this case, it will oxidize the iodide ions (I⁻) present in KI. 3. **Determine the Oxidation Process**: The iodide ion (I⁻) is oxidized to iodate ion (IO3⁻). The oxidation state of iodine in I⁻ is -1, and in IO3⁻, it is +5. 4. **Write the Balanced Reaction**: The balanced chemical reaction in alkaline medium can be expressed as: \[ 2 KMnO_4 + 3 KI + 4 H_2O \rightarrow 2 MnO_2 + 3 KIO_3 + 4 KOH \] Here, KMnO4 is reduced to MnO2, and I⁻ is oxidized to IO3⁻. 5. **Conclusion**: Therefore, when alkaline KMnO4 reacts with KI, the iodide ion is oxidized to iodate ion (IO3⁻). ### Final Answer: The iodide ion is oxidized to **IO3⁻** (iodate ion). ---

To solve the question regarding the oxidation of iodide ions by alkaline KMnO4, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Reactants**: The reactants in this reaction are potassium permanganate (KMnO4) and potassium iodide (KI) in an alkaline medium. 2. **Understand the Role of KMnO4**: ...
Doubtnut Promotions Banner Mobile Dark
|

Topper's Solved these Questions

  • THE D- AND F- BLOCK ELEMENTS

    NCERT FINGERTIPS ENGLISH|Exercise ASSERTION & REASON|15 Videos
  • THE D- AND F- BLOCK ELEMENTS

    NCERT FINGERTIPS ENGLISH|Exercise Electronic Configuration Of D Block Elements|3 Videos
  • THE D- AND F- BLOCK ELEMENTS

    NCERT FINGERTIPS ENGLISH|Exercise HOTS|10 Videos
  • SURFACE CHEMISTRY

    NCERT FINGERTIPS ENGLISH|Exercise Assertion And Reason|15 Videos
  • THE P-BLOCK ELEMENTS

    NCERT FINGERTIPS ENGLISH|Exercise Assertion And Reason|15 Videos

Similar Questions

Explore conceptually related problems

KMnO_(4) acts as an oxidising agent in acidic medium. The number of moles of KMnO_(4) that will be needed to react with one mole of sulphide ions in acidic solution is

Acetylene react with alkaline KMnO_(4) to give

Knowledge Check

  • KMnO_(4) acts as an oxidising agent in acidic medium. The number of moles of KMnO_(4) that will be needed to react with one mole of sulphide ions in acidic solution is

    A
    `2/5`
    B
    `3/5`
    C
    `4/5`
    D
    `1/5`
  • KMnO_(4) acts as an oxidising agent in acidic medium. The number of moles of KMnO_(4) that will be needed to react with one mole of sulphide ions in acidic solution is

    A
    `2//5`
    B
    `3//5`
    C
    `4//5`
    D
    `1//5`
  • Similar Questions

    Explore conceptually related problems

    Alkaline KMnO_(4) . Oxidizes acetylene to -

    KMnO_(4) oxidises I^(-) to I_(2) in acidic medium. The equivalent weight of KMnO_(4) is :

    KMnO_(4) is a strong oxidising agent in acidic medium. To provide acidic medium H_(2)SO_(4) is used instead of HCl. This is because

    Oxidation of o-xylene with alkaline KMnO_(4) gives…….

    STATEMENT-1 KMnO_(4) acts as powerful oxidising agent in acids, alkaline and neutral medium. STATEMENT-2: Equivalent weight of KMnO_(4) in acidic medium in M/5 and in strongly alkaline medium in M/3. STATEMENT-3 : KMnO_(4) solution is used as a primary standard and acts as self indicator during its titration more Mohr salt.

    Oxidation of But-2-yne with alkaline KMnO_4 gives :