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The radius of hydrogen atom in the groun...

The radius of hydrogen atom in the ground state `0.53 Å`. The radius of `Li^(2+)` ion (Atomic number = 3) in a similar state is

A

(a) 1.06 Å

B

(b) 0.265 Å

C

(c) 0.17 Å

D

(d) 0.53 Å

Text Solution

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The correct Answer is:
To find the radius of the `Li^(2+)` ion in the ground state, we can use the formula derived from Bohr's theory of atomic structure. The radius of an atom in a particular state is given by the formula: \[ r = \frac{n^2}{Z} \times r_H \] where: - \( r \) is the radius of the atom, - \( n \) is the principal quantum number (which is 1 for the ground state), - \( Z \) is the atomic number, - \( r_H \) is the radius of the hydrogen atom in the ground state (0.53 Å). ### Step-by-Step Solution: 1. **Identify the parameters:** - For hydrogen (H), the radius in the ground state \( r_H = 0.53 \, \text{Å} \). - The atomic number \( Z \) for lithium ion \( Li^{2+} \) is 3. - The principal quantum number \( n \) for the ground state is 1. 2. **Use the formula for the radius:** \[ r = \frac{n^2}{Z} \times r_H \] 3. **Substitute the values into the formula:** \[ r = \frac{1^2}{3} \times 0.53 \, \text{Å} \] 4. **Calculate the radius:** \[ r = \frac{1}{3} \times 0.53 \, \text{Å} = 0.1767 \, \text{Å} \] 5. **Round the answer:** \[ r \approx 0.17 \, \text{Å} \] ### Final Answer: The radius of the `Li^(2+)` ion in the ground state is approximately \( 0.17 \, \text{Å} \). ---

To find the radius of the `Li^(2+)` ion in the ground state, we can use the formula derived from Bohr's theory of atomic structure. The radius of an atom in a particular state is given by the formula: \[ r = \frac{n^2}{Z} \times r_H \] where: - \( r \) is the radius of the atom, - \( n \) is the principal quantum number (which is 1 for the ground state), - \( Z \) is the atomic number, ...
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