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The correct sequence of the oxidation st...

The correct sequence of the oxidation state of underlined elements is
`Na_(2)[ul(Fe)(CN)_(5)NO],K_(2)ul(Ta)F_(7),Mg_(2)ul(P)_(2)O_(7),Na_(2)ul(S)_(4)O_(6),ul(N)_(3)H`

A

`+3, +5, +5, +2.5, -(1)/(3)`

B

`+5, +3, +5, +3, +(1)/(3)`

C

`+3, +3, +5, +5, -(1)/(3)`

D

`+5,+5, +3, +2.5,+(1)/(3)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the correct sequence of the oxidation states of the underlined elements in the given compounds, we will calculate the oxidation states step by step for each compound. ### Step 1: Calculate the oxidation state of Iron (Fe) in Na₂[Fe(CN)₅NO] 1. **Identify the oxidation states of known elements:** - Sodium (Na) has an oxidation state of +1. - Carbon (C) in cyanide (CN) has an oxidation state of +4, while nitrogen (N) has an oxidation state of -3. Thus, CN as a whole has an oxidation state of -1. - The oxidation state of NO (nitric oxide) is 0. 2. **Set up the equation:** \[ 2(+1) + x + 5(-1) + 0 = 0 \] \[ 2 + x - 5 = 0 \] \[ x - 3 = 0 \implies x = +3 \] ### Step 2: Calculate the oxidation state of Tantalum (Ta) in K₂TaF₇ 1. **Identify the oxidation states of known elements:** - Potassium (K) has an oxidation state of +1. - Fluorine (F) has an oxidation state of -1. 2. **Set up the equation:** \[ 2(+1) + x + 7(-1) = 0 \] \[ 2 + x - 7 = 0 \] \[ x - 5 = 0 \implies x = +5 \] ### Step 3: Calculate the oxidation state of Phosphorus (P) in Mg₂P₂O₇ 1. **Identify the oxidation states of known elements:** - Magnesium (Mg) has an oxidation state of +2. - Oxygen (O) has an oxidation state of -2. 2. **Set up the equation:** \[ 2(2) + 2x + 7(-2) = 0 \] \[ 4 + 2x - 14 = 0 \] \[ 2x - 10 = 0 \implies 2x = 10 \implies x = +5 \] ### Step 4: Calculate the oxidation state of Sulfur (S) in Na₂S₄O₆ 1. **Identify the oxidation states of known elements:** - Sodium (Na) has an oxidation state of +1. - Oxygen (O) has an oxidation state of -2. 2. **Set up the equation:** \[ 4x + 2(+1) + 6(-2) = 0 \] \[ 4x + 2 - 12 = 0 \] \[ 4x - 10 = 0 \implies 4x = 10 \implies x = +2.5 \] ### Step 5: Calculate the oxidation state of Nitrogen (N) in N₃H 1. **Identify the oxidation states of known elements:** - Hydrogen (H) has an oxidation state of +1. 2. **Set up the equation:** \[ 3x + 3(+1) = 0 \] \[ 3x + 3 = 0 \] \[ 3x = -3 \implies x = -1 \] ### Summary of Oxidation States - Iron (Fe) = +3 - Tantalum (Ta) = +5 - Phosphorus (P) = +5 - Sulfur (S) = +2.5 - Nitrogen (N) = -1 ### Final Sequence of Oxidation States The correct sequence of the oxidation states of the underlined elements is: 1. Fe: +3 2. Ta: +5 3. P: +5 4. S: +2.5 5. N: -1 ### Conclusion The correct order of oxidation states is: +3, +5, +5, +2.5, -1.

To determine the correct sequence of the oxidation states of the underlined elements in the given compounds, we will calculate the oxidation states step by step for each compound. ### Step 1: Calculate the oxidation state of Iron (Fe) in Na₂[Fe(CN)₅NO] 1. **Identify the oxidation states of known elements:** - Sodium (Na) has an oxidation state of +1. - Carbon (C) in cyanide (CN) has an oxidation state of +4, while nitrogen (N) has an oxidation state of -3. Thus, CN as a whole has an oxidation state of -1. - The oxidation state of NO (nitric oxide) is 0. ...
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