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In the reaction :Cl(2)+OH^(-)rarrCl^(-)+...

In the reaction `:Cl_(2)+OH^(-)rarrCl^(-)+ClO_(4)^(-)+H_(2)O` :-

A

Chlorine is oxidised

B

Chlorine is reduced.

C

Chlorine is oxidised as well as reduced.

D

Chlorine is neither oxidised nor reduced.

Text Solution

AI Generated Solution

The correct Answer is:
To analyze the redox reaction \( \text{Cl}_2 + \text{OH}^- \rightarrow \text{Cl}^- + \text{ClO}_4^- + \text{H}_2\text{O} \), we will follow these steps: ### Step 1: Identify the oxidation states of chlorine in the reactants and products. - In \( \text{Cl}_2 \), the oxidation state of chlorine is **0** (since it is in its elemental form). - In \( \text{Cl}^- \), the oxidation state of chlorine is **-1**. - In \( \text{ClO}_4^- \), we need to calculate the oxidation state of chlorine: - Let the oxidation state of Cl be \( x \). - The equation for the oxidation state is: \[ x + 4(-2) = -1 \] \[ x - 8 = -1 \implies x = +7 \] - Therefore, the oxidation state of chlorine in \( \text{ClO}_4^- \) is **+7**. ### Step 2: Determine the changes in oxidation states. - Chlorine changes from **0** in \( \text{Cl}_2 \) to **-1** in \( \text{Cl}^- \) (reduction). - Chlorine changes from **0** in \( \text{Cl}_2 \) to **+7** in \( \text{ClO}_4^- \) (oxidation). ### Step 3: Identify the oxidation and reduction processes. - **Reduction**: The species that gains electrons (decrease in oxidation state) is \( \text{Cl}_2 \) to \( \text{Cl}^- \). - **Oxidation**: The species that loses electrons (increase in oxidation state) is \( \text{Cl}_2 \) to \( \text{ClO}_4^- \). ### Step 4: Conclusion Since chlorine undergoes both oxidation and reduction in this reaction, we conclude that chlorine is both oxidized and reduced. ### Final Answer The correct option is: **Chlorine is oxidized as well as reduced.** ---

To analyze the redox reaction \( \text{Cl}_2 + \text{OH}^- \rightarrow \text{Cl}^- + \text{ClO}_4^- + \text{H}_2\text{O} \), we will follow these steps: ### Step 1: Identify the oxidation states of chlorine in the reactants and products. - In \( \text{Cl}_2 \), the oxidation state of chlorine is **0** (since it is in its elemental form). - In \( \text{Cl}^- \), the oxidation state of chlorine is **-1**. - In \( \text{ClO}_4^- \), we need to calculate the oxidation state of chlorine: - Let the oxidation state of Cl be \( x \). - The equation for the oxidation state is: ...
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