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Assertion : Sn in +2 oxidation state is ...

Assertion : Sn in +2 oxidation state is a reducing agent while Pb in + 4 state is an oxidising agent.
Reason : Inert pair effect is due to participation of s electrons in bond formation.

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To analyze the assertion and reason provided in the question, we can break it down step by step. ### Step 1: Understanding the Assertion The assertion states that Sn in the +2 oxidation state acts as a reducing agent while Pb in the +4 oxidation state acts as an oxidizing agent. - **Explanation**: - A reducing agent is a substance that donates electrons to another substance and is oxidized in the process. - Sn in the +2 state can be oxidized to Sn in the +4 state, meaning it can lose electrons and thus act as a reducing agent. - Pb in the +4 state can gain electrons to be reduced to Pb in the +2 state, meaning it can accept electrons and thus acts as an oxidizing agent. ### Step 2: Understanding the Reason The reason states that the inert pair effect is due to the participation of s electrons in bond formation. - **Explanation**: - The inert pair effect refers to the tendency of the s electrons (in the outermost shell) to remain non-bonding or "inert" as we move down the group in the periodic table. - This effect is actually due to the non-participation of s electrons in bond formation, not their participation. Thus, the reason provided is incorrect. ### Step 3: Conclusion - The assertion is true because Sn in +2 state is indeed a reducing agent and Pb in +4 state is an oxidizing agent. - The reason is false because it incorrectly describes the inert pair effect as a participation of s electrons in bond formation. ### Final Answer - **Assertion**: True - **Reason**: False

To analyze the assertion and reason provided in the question, we can break it down step by step. ### Step 1: Understanding the Assertion The assertion states that Sn in the +2 oxidation state acts as a reducing agent while Pb in the +4 oxidation state acts as an oxidizing agent. - **Explanation**: - A reducing agent is a substance that donates electrons to another substance and is oxidized in the process. - Sn in the +2 state can be oxidized to Sn in the +4 state, meaning it can lose electrons and thus act as a reducing agent. ...
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