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Wurtz reaction is used to unit...

Wurtz reaction is used to unit

A

two alkyl halides

B

two aryl halides

C

alkyl and aryl halides

D

two benzene units.

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**Step-by-Step Solution:** 1. **Understanding Wurtz Reaction:** The Wurtz reaction is a coupling reaction that involves the reaction of alkyl halides with sodium metal. It is typically used to synthesize symmetrical alkanes. 2. **Reaction Conditions:** The Wurtz reaction requires: - Two moles of alkyl halide (R-X) - One mole of sodium metal (Na) - Anhydrous ether as a solvent (usually dry ether) 3. **Mechanism of the Reaction:** - The sodium metal donates electrons to the alkyl halide, generating free radicals. - These free radicals then couple together to form a new carbon-carbon bond, resulting in a symmetrical alkane. 4. **Product Formation:** - The general reaction can be represented as: \[ 2 \text{R-X} + 2 \text{Na} \rightarrow \text{R-R} + 2 \text{NaX} \] - Here, R-R represents the symmetrical alkane formed, and NaX is the sodium halide byproduct. 5. **Limitations of Wurtz Reaction:** - If different alkyl halides are used, a mixture of products can be formed instead of a single symmetrical alkane. - The Wurtz reaction is specific to alkyl halides and does not apply to aryl halides. 6. **Comparison with Fitting Reaction:** - While Wurtz reaction involves alkyl halides, the Fitting reaction involves the coupling of aryl halides (such as phenyl halides) and is not considered a Wurtz reaction. 7. **Conclusion:** - The Wurtz reaction is primarily used to unite alkyl halides to form symmetrical alkanes.

**Step-by-Step Solution:** 1. **Understanding Wurtz Reaction:** The Wurtz reaction is a coupling reaction that involves the reaction of alkyl halides with sodium metal. It is typically used to synthesize symmetrical alkanes. 2. **Reaction Conditions:** The Wurtz reaction requires: - Two moles of alkyl halide (R-X) ...
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Knowledge Check

  • Which of the following alkanes cannot be synthesized by the Wurtz reaction in good yield?

    A
    B
    C
    D
  • Wurtz reaction using bromoethane yields

    A
    (i) 2-bromobutane
    B
    (ii) n-butane
    C
    (iii) iso-butane
    D
    (iv) ethane.
  • Assertion: Wurtz reaction is not preferred for the preparation of alkanes containing odd number of carbon atoms. Reason: It is not possible to prepare alkanes with odd number of carbon atoms through wurtz reaction.

    A
    If both assertion and reson are true and reason is the correct explanation of assertion
    B
    If both assertion and reason are true but reason is not the correct explanation of assertion.
    C
    If assertion is true but reason is false.
    D
    If both assertion and reason are false.
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    Wurtz reaction of methyl iodide yields an organic compound X. Which one of the following reactions also yields X?

    n- Butance (C_(4)H_(10)) is produced by monobromation of C_(2)H_(6) followed by the Wurtz reaction. Calculate the volume of ethane at STP requried to produce 55 g of n-butane. The bromination takes place with 90% yield and the Wurtz reaction with 85% yield.