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Which of the following alkynes can be id...

Which of the following alkynes can be identified and distinguished from the rest of the alkynes on reaction with ammoniacal silver nitrate to gave a white presipitate?

A

`CH_(3)C-=C-CH_(3)`

B

`CH_(3)CH_(2)C-=CH`

C

`CH_(3)CH_(2)C-=C CH_(3)`

D

`CH_(3)C-=C CH_(2)CH_(2)CH_(3)`

Text Solution

Verified by Experts

The correct Answer is:
B

Only terminal alkynes react with ammoniacal silver nitrate to give white precipitate of silver acetylides.
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Knowledge Check

  • Which of the following alkynes is most acidic?

    A
    `CH_(3)C-=CH`
    B
    `CH_(3)C-=C CH_(3)`
    C
    `CH_(3)CH_(2)C-=CH`
    D
    `CH-=CH`
  • Which of the following reagents can be distinguish propyne from propene?

    A
    `Br_(2),C Cl_(4)`
    B
    Dilute `KMnO_(4)`
    C
    Conc. `H_(2)SO_(4)`
    D
    `AgNO_(3)" in "NH_(4)OH`
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