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Benzene easily shows...

Benzene easily shows

A

ring fission reactions since it is unstable

B

addition reactions since it is unsaturated

C

electrophilic substitution reactions due to stable ring and high `pi` electron density

D

nucleophilic substitution reactions due to stable ring and minimum electron density.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question "Benzene easily shows," we need to analyze the options provided and determine which reactions benzene can undergo based on its structure and properties. ### Step-by-Step Solution: 1. **Understanding Benzene Structure**: - Benzene (C₆H₆) is a cyclic hydrocarbon with a ring of six carbon atoms, each bonded to one hydrogen atom. - It has alternating double bonds, but due to resonance, the electrons are delocalized, making benzene very stable. **Hint**: Remember that benzene is an aromatic compound with a unique structure that contributes to its stability. 2. **Evaluating Ring Fission Reaction**: - A ring fission reaction involves breaking the benzene ring. However, benzene is very stable due to resonance and does not easily undergo ring fission. - Therefore, this option is incorrect. **Hint**: Consider the stability of benzene and its aromatic nature when thinking about reactions that involve breaking the ring. 3. **Evaluating Addition Reactions**: - Benzene can theoretically undergo addition reactions due to its unsaturation (presence of double bonds). However, due to the delocalization of π electrons, it prefers to undergo substitution reactions instead. - Thus, benzene does not easily show addition reactions like alkenes do. **Hint**: Think about how the delocalized electrons in benzene affect its reactivity compared to alkenes. 4. **Evaluating Electrophilic Substitution Reaction**: - Benzene readily undergoes electrophilic substitution reactions. In these reactions, an electrophile replaces one of the hydrogen atoms on the benzene ring. - The high electron density in the π system makes it susceptible to attack by electrophiles, leading to the formation of a carbocation intermediate. **Hint**: Focus on how the high electron density in benzene makes it reactive towards electrophiles. 5. **Evaluating Nucleophilic Substitution Reaction**: - Benzene does not undergo nucleophilic substitution reactions because nucleophiles also have high electron density. The electron-rich nature of benzene makes it less likely to react with other electron-rich species. - Therefore, this option is incorrect. **Hint**: Recall that nucleophiles require a substrate that can accommodate their electron density, which benzene cannot due to its stability. ### Conclusion: Based on the analysis, the correct answer is that benzene easily shows **electrophilic substitution reactions** due to its stable aromatic structure and high π electron density. ### Final Answer: Benzene easily shows **electrophilic substitution reactions**.
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Knowledge Check

  • A liquid pair of benzene-toluene shows :

    A
    Positive deviation from Raoult's law
    B
    Negative deviation from Raoult's law.
    C
    Practically no deviation from Raoult's law
    D
    Irregular deviation from Raoult's law.
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