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Which of the following IUPAC names is no...

Which of the following IUPAC names is not correctly matched?

A

B

`(CH_(3))_(2)C=CHCOOH` : 3-Methylbut-2-enoic acid

C

`PhCH_(2)CH_(2)COOH`: 3-Phenylpropanoic acid

D

Text Solution

AI Generated Solution

The correct Answer is:
To determine which of the given IUPAC names is not correctly matched, we will analyze each option step by step. ### Step 1: Analyze Option A 1. **Structure Identification**: Identify the structure of the compound. It is a cyclic compound with five carbon atoms (cyclopentane) and a carboxylic acid functional group. 2. **Numbering**: Start numbering from the carbon with the carboxylic acid group to give the substituents the lowest possible numbers. The numbering goes as follows: - 1 (carboxylic acid), 2 (methyl), 3, 4, 5. 3. **Substituent Identification**: The substituent is a methyl group on the second carbon. 4. **Naming**: The name should be 2-methylpentanoic acid. However, the option does not match this name correctly. ### Step 2: Analyze Option B 1. **Structure Identification**: This compound has a four-carbon chain (butane) with a carboxylic acid group and a methyl group. 2. **Numbering**: Number the chain starting from the end closest to the carboxylic acid: - 1 (carboxylic acid), 2, 3 (methyl), 4. 3. **Substituent Identification**: The substituent is a methyl group on the third carbon. 4. **Naming**: The correct name is 3-methylbutanoic acid. This matches the given name. ### Step 3: Analyze Option C 1. **Structure Identification**: This compound has a propane chain with a phenyl group as a substituent. 2. **Numbering**: Number the chain starting from the end closest to the carboxylic acid: - 1 (carboxylic acid), 2, 3 (phenyl). 3. **Substituent Identification**: The substituent is a phenyl group on the third carbon. 4. **Naming**: The correct name is 3-phenylpropanoic acid. This matches the given name. ### Step 4: Analyze Option D 1. **Structure Identification**: This compound has a benzene ring with three nitro groups and a carboxylic acid group. 2. **Numbering**: Number the benzene ring to give the nitro groups the lowest possible numbers: - 1 (carboxylic acid), 2 (nitro), 4 (nitro), 6 (nitro). 3. **Substituent Identification**: The substituents are nitro groups at positions 2, 4, and 6. 4. **Naming**: The correct name is 2,4,6-trinitrobenzoic acid. This matches the given name. ### Conclusion After analyzing all options, it is clear that **Option A** is the incorrectly matched IUPAC name. The correct name should be 2-methylpentanoic acid, but it does not match the provided name. ### Final Answer **Option A is not correctly matched.** ---

To determine which of the given IUPAC names is not correctly matched, we will analyze each option step by step. ### Step 1: Analyze Option A 1. **Structure Identification**: Identify the structure of the compound. It is a cyclic compound with five carbon atoms (cyclopentane) and a carboxylic acid functional group. 2. **Numbering**: Start numbering from the carbon with the carboxylic acid group to give the substituents the lowest possible numbers. The numbering goes as follows: - 1 (carboxylic acid), 2 (methyl), 3, 4, 5. 3. **Substituent Identification**: The substituent is a methyl group on the second carbon. 4. **Naming**: The name should be 2-methylpentanoic acid. However, the option does not match this name correctly. ...
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NCERT FINGERTIPS ENGLISH-ALDEHYDES, KETONES AND CARBOXYLIC ACIDS-MCQs( NOMENCLATURE AND STRUCTURE OF CARBOXYL GROUP )
  1. Which of the following IUPAC names is not correctly matched?

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  2. The correct structure representation of carboxylate ion is

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