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Compound Ph-O-overset(O)overset("||")C-P...

Compound `Ph-O-overset(O)overset("||")C-Ph` can be prepared by the reaction of _______ .

A

phenol and benzoic acid in the presence of NaOH

B

phenol and benzoyl chloride in the presence of pyridine

C

phenol and benzoyl chloride in the presence of `ZnCl_(2)`

D

phenol and benzaldehyde in the presence of palladium

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the preparation of the compound `Ph-O-C(=O)-Ph` (phenyl benzoate), we can follow these steps: ### Step 1: Identify the Structure The compound `Ph-O-C(=O)-Ph` consists of a phenyl group (Ph) attached to an oxygen (O) which is further connected to a carbonyl group (C=O) and another phenyl group. This structure is known as phenyl benzoate. ### Step 2: Determine Possible Reactions To prepare phenyl benzoate, we need to consider the types of reactions that can form esters. One common method is the reaction between a phenol and an acyl chloride (acid chloride). ### Step 3: Analyze the Given Options 1. **Option 1**: Phenol and Benzoic Acid - This reaction cannot proceed because benzoic acid cannot act as an electrophile in this context. 2. **Option 2**: Phenol and Benzoyl Chloride - This is a viable option. Phenol can act as a nucleophile, and benzoyl chloride can provide the electrophile needed for the reaction. The reaction would yield phenyl benzoate. 3. **Option 3**: Involves ZnCl2 - This option is incorrect as it does not provide the necessary reactants to form phenyl benzoate. 4. **Option 4**: Phenol and Benzaldehyde - This option is also incorrect because benzaldehyde cannot provide a suitable electrophile for the nucleophilic attack by phenol. ### Step 4: Conclusion The correct answer is **Option 2: Phenol and Benzoyl Chloride** in the presence of a base like pyridine, which facilitates the reaction by deprotonating phenol to form a more reactive nucleophile. ### Final Answer Compound `Ph-O-C(=O)-Ph` can be prepared by the reaction of **Phenol and Benzoyl Chloride**. ---
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Treatement of compound Ph-O-overset(O)overset(||)(C)-Ph with NaOH solution yields

Write the systematic IUPAC names of the following compounds : H-overset(O) overset(||) C-overset(O ) overset(||) C - H

Knowledge Check

  • Mixture of Ph-overset(O)overset(||)(C)-H and HCHO is treated with NaOH then Cannizzaro reaction involves

    A
    reduction of HCHO
    B
    oxidation of HCHO
    C
    reduction of PhCHO
    D
    oxidation of PhCHO
  • Compound having -overset(O)overset(||)(C)-CH_(3) group reacts rapidly with halogen in presence of a base to form haloform. The reaction is known as haloform. R-overset(O)overset(||)(C)-CH_(3)overset(X_(2)+overset(ϴ)(O)H)(to)R-overset(O)overset(||)(C)-overset(ϴ)(O)+CHX_(3) Mechanism Consider the following reactions: Reaction I toPh-overset(O)overset(||)(C)-CH_(3)overset(Cl_(2),overset(ϴ)(O)H)(to)Ph-overset(O)overset(||)(C)-overset(ϴ)(O)+CHCl_(3) Reaction II toPh-overset(O)overset(||)(C)-CD_(3)-overset(Cl_(2),overset(ϴ)(O)H)(to)Ph-overset(O)overset(||)(C)-overset(ϴ)(O)+CDCl_(3) Which of the following is correct comparison of the rate of reaction I and II?

    A
    `r_(I)gtr_(II)`
    B
    `r_(I)gtr_(II)`
    C
    `r_(I)=r_(II)`
    D
    Cannot be determined
  • Compound having -overset(O)overset(||)(C)-CH_(3) group reacts rapidly with halogen in presence of a base to form haloform. The reaction is known as haloform. R-overset(O)overset(||)(C)-CH_(3)overset(X_(2)+overset(ϴ)(O)H)(to)R-overset(O)overset(||)(C)-overset(ϴ)(O)+CHX_(3) Mechanism Which of the following will yield iodoform on reaction with I_(2)+NaOH ?

    A
    B
    C
    D
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    Ph-overset(O)overset(||)(C)-CH_(3)+underset("(excess)")(CH_(2)=O) overset(OH^(Theta))toPh-overset(O)overset(||)(C)-C(CH_(2)OH)_(3) In the above reaction how times of aldol reaction takes place ?

    Ph-CHO+Ph-CHOoverset(Na_(2)[Fe(CO)_(4)])rarrPh-overset(O)overset("||")C-OCH_(2)-Ph . This reaction is known as :

    Compound having -overset(O)overset(||)(C)-CH_(3) group reacts rapidly with halogen in presence of a base to form haloform. The reaction is known as haloform. R-overset(O)overset(||)(C)-CH_(3)overset(X_(2)+overset(ϴ)(O)H)(to)R-overset(O)overset(||)(C)-overset(ϴ)(O)+CHX_(3) Mechanism Which of the following is correct comparisonof rate of haloform reaction with various halogens?

    Ph- CH = CH - overset(O)overset(||) C - OH The IUPAC name is :

    CH_(3)-overset(O)overset(||)(C)-H and Ph-overset(O)overset(||)(C)-H can be differentiated by :