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Which alcohols contain the -OH group att...

Which alcohols contain the `-OH` group attached to a `sp^(3)-` hybridised carbon atom next to an aromatic ring?

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Read the given passage and answer questions follow : The replacement of hydrogen atom(s) in an aliphatic or aromatic hydrocarbon by halogen atom(s) results in the formation of alkyl halide (haloalkane) and aryl halide (haloarene),respectively. Haloalkanes contain halogen atom(s) attached to the sp^(3) hybridised carbon atom of an alkyl group whereas haloarenes contain halogen atom(s) attached to sp^(2) hybridised carbon atom(s) of an aryl group. Many halogen containing organic compounds occur in nature and some of these are clinically useful. These classes of compounds find wide applications in industry as well as in day-to-day life. They are used as solvents for relatively non-polar compounds and as starting materials for the synthesis of wide range of organic compounds. Chlorine containing antibiotic, chloramphenicol, produced by microorganisms is very effective for the treatment of typhoid fever. Our body produces iodine containing hormone, thyroxine, the deficiency of which causes a disease called goiter. Synthetic halogen compounds, viz. chloroquine is used for the treatment of malaria, halothane is used as an anaesthetic during surgery. Out of C_(2)H_(5)Cl " and " C_(6)H_(5)Cl halogen compounds, which has the halogen attached to sp^(2) hybridised carbon atom ?

Haloalkanes contain halogen atom(s) attached to the sp^(3) hybridised carbon atom of an alkyl group. Identify haloalkene from the following compounds.

Knowledge Check

  • In _________ alcohols , the -OH group is attached to a sp^2 hybridised carbon atom.

    A
    allylic
    B
    benzylic
    C
    vinylic
    D
    all of these
  • Haloalkanes contain halogen atom (s) attached to the sp^(3) hybridised carbon atom of an alkyl group. Identify haloalkane from the following compounds.

    A
    2-Bromopentane
    B
    Vinyl chloride (chloroethene)
    C
    2-chloroacetophenone
    D
    Trichloromethane
  • Haloalkanes contain halogen atom (s) attached to the sp^(3) hybridised carbon atom of an alkyl group. Identify haloalkane from the following compounds.

    A
    2-Bromopentane
    B
    Vinyl chloride (chloroethene)
    C
    2-chloroacetophenone
    D
    Trichloromethane
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    In vinyl alcohol -OH group is attached to

    In allylic alcohol - OH group is attached to

    Benzene carbaldehyde is reacted with concentrated NaOH solution, to give the products 'A' and 'B'. The prodcut 'B' is an aromatic hydroxy compounds where OH group in linked to sp^(3) hybridised carbon atom next to benzene ring. The products 'A' and 'B' are respectibvely:

    A chemist isolated a compound A with molecular formula C_(7)H_(13) Br . A undergoes very fast S_(N)1 reaction. Spectroscopic evidence indicated that compound A has the following structural characteristics. . It contains fnive sp_(3) hybridised carbon atoms. Among those five SP^(3 ) carbon atoms are three methyl groups, one CH_(2) group and one CH group. . It also contains two SP_(2) -hybridised carbon atoms . Also there is only one hydrogen atom attched to sp^(2) carbons. . The compound contains a total of six allylic hydrogen atoms. . The carbon atom that holds the Br has one H attached to it. When compound A reacts with boiling water , it undergoes an S_(N)1 reaction and produces. two principal products B and C . Both B and C are alcohols with their molecular formula C_(7)H_(14)O . Among the two alcohols, B has the --OH group attached to an sP_(3) carbon atom that has no H atoms bonded to it . What can be said about the isomerism shown by the two alcohols B and C ?

    A chemist isolated a compound A with molecular formula C_(7)H_(13) Br . A undergoes very fast S_(N)1 reaction. Spectroscopic evidence indicated that compound A has the following structural characteristics. . It contains fnive sp_(3) hybridised carbon atoms. Among those five SP^(3 ) carbon atoms are three methyl groups, one CH_(2) group and one CH group. . It also contains two SP_(2) -hybridised carbon atoms . Also there is only one hydrogen atom attched to sp^(2) carbons. . The compound contains a total of six allylic hydrogen atoms. . The carbon atom that holds the Br has one H attached to it. When compound A reacts with boiling water , it undergoes an S_(N)1 reaction and produces. two principal products B and C . Both B and C are alcohols with their molecular formula C_(7)H_(14)O . Among the two alcohols, B has the --OH group attached to an sP_(3) carbon atom that has no H atoms bonded to it . If the starting compound A is brominated in gas phase in presence of a Lewis acid catalys, a tribromide would result from addition of Br_(2) to C=C . How many different structures of stereo isomers isomers can be drawn for this tribromide ?