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The positive value of the standard elect...

The positive value of the standard electrode potential of `Cu^(2+)//Cu` indicates that ____

A

this redox couple is a stronger reducing agent than the `H^(+)//H_(2)` couple.

B

this redox couple is a stronger oxidising agent than `H^(+)//H_(2)`.

C

Cu can displace `H_(2)` from acid.

D

Cu cannot displace `H_(2)` from acid.

Text Solution

Verified by Experts

The correct Answer is:
B, D

* `(E_(H^(+)|H_(2))^(Theta)) lt (E_(Cu^(2+)|Cu)^(Theta))`
So following reaction is possible.
`Cu_((aq))^(2+)+H_(2(g)) to Cu_((S)) +2H_((aq))^(+)`
* Here, hydrogen is oxidized and `Cu^(2+)|Cu` is strong oxidizing agent.
* The electrode having more `E^(@)` value will act as strong oxidizing agent. Cu does not get oxidized in this reaction. Cu does not replace `H_(2)` from the acid.
* Lower the value of standard reduction potential higher will be the reducing power.
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Knowledge Check

  • Which cell will measure standard electrode potential of copper electrode ?

    A
    `Pt_((S))|H_(2(g,0.1" bar"))|H_((aq,1M))^(+)||Cu_((aq,1M))^(2+)|Cu`
    B
    `Pt_((S))|H_(2(g,1" bar"))|H_((aq,1M))^(+)||Cu_((aq,2M))^(2+)|Cu`
    C
    `Pt_((S))|H_(2(g,1" bar"))|H_((aq,0.1M))^(+)||Cu_((aq,1M))^(2+)|Cu`
    D
    `Pt_((S))|H_(2(g,1" bar"))|H_((aq,1M))^(+)||Cu_((aq,1M))^(2+)|Cu`
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